Experiments upon magnesia alba, Quicklime, and some other Alcaline SubstancesBlack, Joseph
Science
Experiments upon magnesia alba, Quicklime, and some other Alcaline Substances
Black, Joseph
Alkalies; Carbon dioxide; Chemistry -- Early works to 1800; Phlogiston
Imagining that I perceived some resemblance between the properties of
_magnesia_ and those of alkalis, I was led to try what change this
substance would suffer from the addition of quick-lime, which alters in
such a peculiar manner the alkaline salts.
Twenty seven grains of _magnesia_ in fine powder were mixed with
eighteen ounces of lime-water in a flask, which was corked close and
shaken frequently for four days. During this time, I frequently dipp'd
into it little bits of paper, which were coloured with the juice of
violets; and these became green as soon as they touched the water, until
the fourth day, when their colour did not seem to be altered. The water
being now poured off, was intirely insipid, and agreed in every
chemical trial with pure water. The powder, after being perfectly well
dried, weighed thirty seven grains. It did not dissolve intirely in
spirit of vitriol; but, after a brisk effervescence, part of it subsided
in the same manner as the calcarious earths, when mixed with this acid.
When I first tried this experiment, I was at the trouble of digesting
the mixture in the heat of boiling water, and did not then know that it
would succeed in the heat of the air. But Dr. _Alston_, who has obliged
the world with many curious and useful discoveries on the subject of
quick-lime, having had occasion to repeat it, I learned from him that
heat is not necessary; and he has moreover added an useful purpose to
which this property of _magnesia_ may be applied; I mean the sweetening
of water at sea, with which lime may have been mixed to prevent its
putrefaction.
That part of the dried powder which does not dissolve in spirit of
vitriol, consists of the lime separated from the water.
Quick-lime itself is also rendered mild by _magnesia_, if these two are
well rubbed together and infused with a small quantity of water.
By the following experiments, I proposed to know whether this substance
could be reduced to a quick-lime.
An ounce of _magnesia_ was exposed in a crucible for about an hour to
such a heat as is sufficient to melt copper. When taken out, it weighed
three drams and one scruple, or had lost 7/12 of its former weight.
I repeated, with the _magnesia_ prepared in this manner, most of those
experiments I had already made upon it before calcination, and the
result was as follows.
It dissolves in all the acids, and with these composes salts exactly
similar to those described in the first set of experiments: but what is
particularly to be remarked, it is dissolved without any the least
degree of effervescence.
It slowly precipitates the corrosive sublimate of mercury in the form of
a black powder.
It separates the volatile alkali in salt ammoniac from the acid, when it
is mixed with a warm solution of that salt. But it does not separate an
acid from a calcarious earth, nor does it induce the least change upon
lime-water.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account