Familiar Letters on Chemistry, and Its Relation to Commerce, Physiology, and Agriculture — John Shaqi
Familiar Letters on Chemistry, and Its Relation to Commerce, Physiology, and AgricultureLiebig, Justus, Freiherr von
Science
Familiar Letters on Chemistry, and Its Relation to Commerce, Physiology, and Agriculture
Liebig, Justus, Freiherr von
Chemistry
In order to prepare the soda of commerce (which is the carbonate)
from common salt, it is first converted into Glauber's salt
(sulphate of soda). For this purpose 80 pounds weight of
concentrated sulphuric acid (oil of vitriol) are required to 100
pounds of common salt. The duty upon salt checked, for a short time,
the full advantage of this discovery; but when the Government
repealed the duty, and its price was reduced to its minimum, the
cost of soda depended upon that of sulphuric acid.
The demand for sulphuric acid now increased to an immense extent;
and, to supply it, capital was embarked abundantly, as it afforded
an excellent remuneration. The origin and formation of sulphuric
acid was studied most carefully; and from year to year, better,
simpler, and cheaper methods of making it were discovered. With
every improvement in the mode of manufacture, its price fell; and
its sale increased in an equal ratio.
Sulphuric acid is now manufactured in leaden chambers, of such
magnitude that they would contain the whole of an ordinary-sized
house. As regards the process and the apparatus, this manufacture
has reached its acme--scarcely is either susceptible of improvement.
The leaden plates of which the chambers are constructed, requiring
to be joined together with lead (since tin or solder would be acted
on by the acid), this process was, until lately, as expensive as the
plates themselves; but now, by means of the oxy-hydrogen blowpipe,
the plates are cemented together at their edges by mere fusion,
without the intervention of any kind of solder.
And then, as to the process: according to theory, 100 pounds weight
of sulphur ought to produce 306 pounds of sulphuric acid; in
practice 300 pounds are actually obtained; the amount of loss is
therefore too insignificant for consideration.
Again; saltpetre being indispensable in making sulphuric acid, the
commercial value of that salt had formerly an important influence
upon its price. It is true that 100 pounds of saltpetre only are
required to 1000 pounds of sulphur; but its cost was four times
greater than an equal weight of the latter.
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