Faraday, Michael, 1791-1867; Physicists -- Great Britain -- Biography
Completing his circuit, he permitted the current to continue until 'a
reasonable quantity of gas' was collected in the voltameter. The circuit
was then broken, and the quantity of tin liberated compared with the
quantity of gas. The weight of the former was 3.2 grains, that of the
latter 0.49742 of a grain. Oxygen, as you know, unites with hydrogen in
the proportion of 8 to 1, to form water. Calling the equivalent, or as
it is sometimes called, the atomic weight of hydrogen 1, that of oxygen
is 8; that of water is consequently 8 + 1 or 9. Now if the quantity of
water decomposed in Faraday's experiment be represented by the number 9,
or in other words by the equivalent of water, then the quantity of tin
liberated from the fused chloride is found by an easy calculation to be
57.9, which is almost exactly the chemical equivalent of tin. Thus both
the water and the chloride were broken up in proportions expressed
by their respective equivalents. The amount of electric force which
wrenched asunder the constituents of the molecule of water was
competent, and neither more nor less than competent, to wrench asunder
the constituents of the molecules of the chloride of tin. The fact
is typical. With the indications of his voltameter he compared the
decompositions of other substances, both singly and in series. He
submitted his conclusions to numberless tests. He purposely introduced
secondary actions. He endeavoured to hamper the fulfilment of those laws
which it was the intense desire of his mind to see established. But
from all these difficulties emerged the golden truth, that under every
variety of circumstances the decompositions of the voltaic current are
as definite in their character as those chemical combinations which gave
birth to the atomic theory. This law of Electro-chemical Decomposition
ranks, in point of importance, with that of Definite Combining
Proportions in chemistry.
Footnotes to Chapter 6
[1] I copy these words from the printed abstract of a Friday
evening lecture, given by myself, because they remind me of
Faraday's voice, responding to the utterance by an emphatic
'hear! hear!'--Proceedings of the Royal Institution, vol.
ii. p. 132.
[2] In 1838 he expresses himself thus:--'The word current is
so expressive in common language that when applied in the
consideration of electrical phenomena, we can hardly divest
it sufficiently of its meaning, or prevent our minds from
being prejudiced by it.'--Exp. Resear., vol. i. p. 515. ($
1617.)
[3] This conclusion needs qualification. Faraday overlooked
the part played by ozone.
Chapter 7.
Origin of power in the voltaic pile.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account