Field's Chromatography: or Treatise on Colours and Pigments as Used by ArtistsField, George
Science
Field's Chromatography: or Treatise on Colours and Pigments as Used by Artists
Field, George
Color; Colors; Painting -- Technique
The colour of ultramarine is brought out by successive heatings. Green
portions, more or less in quantity, are often formed in the crucibles,
especially on the first ignition. On repeated heating they pass into a
blue tint. Artificial ultramarines are said to be seldom entirely freed
from all traces of the green modification, and are therefore less
beautiful than the natural varieties, having a shade of green or grey.
This defect, however, is certainly not discernible in Guimet's products,
which sometimes incline so much to purple as to require neutralizing
with a little Prussian blue. Depth for depth, the artificial are darker
and less azure than the natural varieties, but the superiority of the
latter consists not so much in their greater purity of hue, although
this is considerable, as in their far greater transparency. The finest
French ultramarine is never so transparent as the native; it is
brilliant, it is powerful, it is permanent, it is nearly--but only
nearly--transparent. Possessing in a subdued degree the characteristics
and qualities of the genuine, it works, washes, and dries well; and is
useful either in figures, draperies, or landscape. Rivalling in depth,
although not equalling in colour, the pure azure of native ultramarine,
it answers to the same acid tests, but is sometimes distinguished
therefrom by the effervescence which ensues on the addition of an acid.
Not a bubble escapes in such case from the natural blue; unless, indeed,
as occasionally happens, it retain a portion of alkali, with which it
may have been combined in the preparation, but from which it should have
been freed. Darkened as a rule by fire, factitious ultramarine becomes
dingy blue, and at last white, when strongly ignited for a long time;
and is, like the true variety, decolourised by ignition in an atmosphere
of hydrogen gas. At a high temperature, this effect is even produced by
silica, whence the unfitness of ultramarine for painting on glass or
porcelain; and simply by a prolonged red heat the blue is rendered
white. Being unaffected by alkalis, it is eligible in mural decoration,
and is particularly adapted to siliceous painting, on account of the
silica and alumina which it contains, two substances with which a
soluble silicate readily unites. If artificial ultramarine be mixed with
a soluble silicate, for example silicate of potash, and be laid on a
properly prepared ground, it will become so firmly fixed, says Mr.
Barff, that no amount of washing nor the slow action of moisture will
remove it, or affect its brilliancy. Judging from the behaviour of
ultramarine, therefore, if the colours employed in siliceous painting
contain silica and alumina, they should adhere as firmly to the surface
on which they are placed; and this is really the case. It is possible to
produce a mixed solution of aluminate and silicate of potash which will
remain liquid for twenty-four hours. If, while in the liquid state,
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account