Field's Chromatography: or Treatise on Colours and Pigments as Used by ArtistsField, George
Science
Field's Chromatography: or Treatise on Colours and Pigments as Used by Artists
Field, George
Color; Colors; Painting -- Technique
Impure air, or sulphuretted hydrogen, browns or blackens white lead,
converting it partially or wholly into sulphide. It would appear from
the recent investigations of Dr. D. S. Price, that white lead is less
liable to be thus affected, when the pictures in which it is used are
exposed to a strong light; also, that when such pictures have so
suffered, a like exposure will restore them. We have ourselves noticed
the rapidity with which an oil rub of white lead that has been damaged
by foul gas, regains its former whiteness when submitted to air and
sunshine. The action of drying oils has been likewise proved to be very
powerful upon sulphide of lead, an exposure to light for a few days only
being sufficient to change a surface of it, coated with a thin layer of
boiled linseed oil, into a white one. Probably, these agents may have a
similar effect upon other pigments injured by sulphuretted hydrogen, and
many of the colours in paintings may be restored by treating them with
boiled linseed oil, and submitting them to a strong light. That the
result is due to oxidation, there can be no doubt. Indeed, the eminent
French chemist, M. Thénard, was consulted some years back upon the means
of bringing to their original whiteness the black spots which had formed
upon a valuable drawing, by the changing of the white lead, and
employed for that purpose oxygenated water. He had ascertained its power
of converting the black sulphide of lead into the white sulphate, and,
by touching the spots with a brush dipped in the fluid, soon succeeded
in restoring the drawing to its primitive state. Here, again, the use of
the agent might doubtless be extended to other colours, to which foul
air is inimical.
In oil painting white lead is essential in the ground, in dead
colouring, in the formation of tints of all colours, and in scumbling,
either alone or mixed with other pigments. It is also the best local
white, when neutralized with ultramarine or black; and it is the true
representative of light, when warmed with Naples yellow, or orange
vermilion or cadmium, or with a mixture of the yellow and either of the
orange pigments, according to the light.
Ordinary white lead is often mixed with considerable quantities of heavy
spar, gypsum, or chalk. These injure it in body and brightness, dispose
it to dry more slowly, keep its place less firmly, and discolour the oil
with which it is applied, as well as prevent it dissolving completely in
boiling dilute potash-ley, a test by which pure white lead may be known.
Public-domain text, read in full here on John Shaqi.
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