Field's Chromatography: or Treatise on Colours and Pigments as Used by ArtistsField, George
Science
Field's Chromatography: or Treatise on Colours and Pigments as Used by Artists
Field, George
Color; Colors; Painting -- Technique
The introduction, in 1834, of this peculiar preparation of oxide of zinc
has proved an incalculable boon to water-colour painters, who formerly
had no white which combined perfect permanency with good body in
working. Its invention obviated the necessity for using white lead, a
pigment which, though it may be employed with comparative safety in oil,
is quite unfitted for water. Since the period of its production, Chinese
white has been generally preferred by water-colour artists, as being the
most eligible in their peculiar department. Previous to that period, the
complaints of whites changing were of constant occurrence; but in no
instance has any picture, in which this white has been used, suffered
from its employment. To the colour of oxide of zinc, sulphuretted
hydrogen is altogether harmless; sulphide of zinc being itself white.
The variety under notice works and washes well, possesses no pasty or
clogging properties, and is prepared beautifully white. Moreover, it has
the desirable quality of dense body; so much so, that, as the painter
works, his effects remain unaltered by the drying of the colour. It may
likewise be safely mixed with all other pigments, the following blending
very satisfactorily with the white for opaque lights--cadmium yellow,
orange, and red; gamboge; aureolin; yellow ochre; vermilion; and light
red. Without the artistic drawbacks of constant white or the chemical
defects of white lead, and retaining the advantages of both, Chinese
white cannot but be considered as a most important addition. It is a
matter of regret that this pigment is not equally efficacious in oil.
15. ZINC WHITE
Is either the anhydrous oxide, the hydrate oxide, or hydrated basic
carbonate of zinc. It varies in opacity and colour according to the mode
of manufacture, and the purity of the compound, but may always be relied
upon as permanent. The whiteness of the best samples rivals that of
white lead, and it is not tarnished like the latter by sulphurous
vapours. In opacity it never equals white lead, and might perhaps serve
advantageously as a glaze over that pigment, either alone or compounded
with other colours; as well as act as a medium of interposition between
white lead and those colours which are injured by it, such as gamboge,
crimson lake, &c. When duly and skilfully prepared the colour and body
of this pigment are sufficient to qualify it for a general use upon the
palette in oil: in water it has been superseded by Chinese white.
Occasionally, starch, chalk, white clay, and carbonate of baryta, are
employed as adulterants; none of which, however, are inimical to
stability.
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