Field's Chromatography: or Treatise on Colours and Pigments as Used by ArtistsField, George
Science
Field's Chromatography: or Treatise on Colours and Pigments as Used by Artists
Field, George
Color; Colors; Painting -- Technique
The red obtained from this substance created a great deal of interest
among printers and dyers on its introduction in 1857, or thereabouts.
For purity and brilliancy of shade it was not excelled by any other
colour, but not being able to stand the effects of air and light, its
employment was limited. We are not aware that murexide has yet been
brought forward as a pigment, and judging from its character as a dye,
it would scarcely enrich the palette. Dyes and pigments have much in
common, and a fugitive dye cannot be expected to furnish a permanent
pigment.
Murexide is produced by the action of ammonia on alloxan, which is
itself derived from the uric acid of guano by treatment with nitric
acid, and was known nearly forty years back to stain the fingers and
nails red. The first murexide sent into the market was a reddish-purple
powder, dissolving in water with a fine purple tint, leaving a little
residue undissolved. Owing to improvements in manufacture, it is now
capable of being prepared almost chemically pure, and with that green
metallic reflection peculiar to several coal-tar salts and the wings of
certain insects. When sulphuretted hydrogen is passed through a
concentrated solution of murexide, it is immediately decoloured; a fact
which renders it likely that murexide pigments would be as liable to
suffer from an impure atmosphere, as from exposure to light and air.
When an alkaline solution of murexide is precipitated by an acid, a
light shining powder results, called purpuric acid. This dissolves in
alkalies, and combines with metalline bases to form various coloured
compounds, termed _Purpurates_. Among them may be mentioned a red
purpurate of lead, a purple-red and a rose-coloured purpurate of
mercury, a purple-red purpurate of silver, a dark red-brown purpurate of
strontia, a crystalline red purpurate of cobalt, a scarlet purpurate of
platinum, a yellow purpurate of zinc, and a green purpurate of baryta.
All of these, however, being more or less soluble in water, and owing
their colours to murexide, would be ill adapted for pigments.
107. _Paille de Mil,_
Or African Cochineal, is a substance obtained from Africa. Whether it
has received its name of cochineal from its appearance or origin is not
clear, but it behaves more like galls and sumac than cochineal, though
it does give a kind of red with alumina mordants. The colours it yields
are deficient in brightness, and it has otherwise been reported
unfavourably of.
108. _Peganum Harmala,_
The seeds of which afford a red colour, has been investigated by the
French, but described as inferior to existing reds both in brilliancy
and stability.
109. _Persulphomolybdates._
Public-domain text, read in full here on John Shaqi.
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