Field's Chromatography: or Treatise on Colours and Pigments as Used by ArtistsField, George
Science
Field's Chromatography: or Treatise on Colours and Pigments as Used by Artists
Field, George
Color; Colors; Painting -- Technique
The metallic compounds formed by the combination of persulphomolybdic
acid with a base are pulverulent, in many cases of a red colour, and for
the most part insoluble in water. With barium, the acid furnishes a
yellowish-red powder, insoluble in, but made denser by water, which
imparts to it a cinnabar colour. With calcium it is said to yield a
scarlet, sparingly soluble in water. With chromium, uranium, lead,
platinum, and copper, it gives a dark red; that from the last metal
turning brown when collected on a filter. It likewise produces reds with
zinc, cadmium, iron, mercury, and tin; of which the last is slightly
soluble in water.
Molybdenum being a rare metal, and persulphomolybdate of potash, the
salt used in the foregoing reactions, difficult to prepare, it is
unlikely that the colours named will rank among the pigments of this
generation. Nevertheless, as we have observed before, such fancy
products should not be altogether ignored, it being quite as well to
have some knowledge of our resources, even though those resources be not
at present available. All the rare metals afford coloured compounds:
tantalum, niobium, pelopium, vanadium, tellurium, titanium, yttrium,
lanthanum, didymium, glucinum, cerium, thorinum, zirconium, palladium,
rhodium, iridium, ruthenium, osmium, indium, thallium, &c.; and it is
just possible that some of these may one day scrape acquaintance with
the palette.
110. _Red Chalk_,
The colouring matter of which is sesquioxide of iron, is used as a
crayon. Some specimens are excessively hard, so much so that they are
difficult to crush, even in an iron mortar; while others have the
consistence of the softest iron-ochres. They vary too in tint from a
fawn colour to the softest brick-red, occasionally being almost as
bright as a mixture of equal weights of vermilion and Venetian red. The
amount of iron oxide present has been found to range from four to
thirty-seven per cent, according to the depth and hardness of the
samples. When a specimen of red chalk tolerably rich, but not too rich,
in iron oxide is finely powdered and strongly ignited, it offers a
remarkable change of colour, becoming a dull sage-green. Perhaps this,
if it were permanent, might prove useful in foliage tints.
111. _Red Precipitate_,
Or mercuric oxide, may be obtained either of a brick-red or
orange-yellow colour. It is destroyed by impure air, and on exposure to
sunshine gradually turns black, being superficially decomposed into
oxygen and metallic mercury or mercurous oxide.
112. _Rose Pink_
Is a coarse kind of lake, produced by dyeing chalk or whitening with
decoction of Brazil wood, peachwood, sapan, bar, camwood, &c. It is a
pigment much used by paper-stainers, and in the commonest distemper
painting, &c., but is too perishable to merit the attention of the
artist.
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