Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.Carvalho, David Nunes
History
Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.
Carvalho, David Nunes
Ink
With the passage of time, the particles in some
inks which are held together on the paper by gummy
vehicles, commence to disintegrate and change from
intense black to the brown color of iron rust, the
"added" color which of itself is fugitive in character,
soon departs; the vegetable astringent separating
from the iron salt decays gradually and disappears
and finally terminates in a mere stain or dust mark
which can be blown off the paper. Sometimes, the
written surface of such paper can be treated by carefully
moistening it with a decoction of nut-galls or its
equivalent in the presence of a weak acid, then if any
iron be present, a measurable degree of restoration of
color will ensue and remain for a short period.
Again, the discoloration of an iron ink may be due to
the character of the paper; if of the cheaper grades
and the bleaching compounds employed in their
manufacture are not thoroughly washed out, then the
ink not only begins to absorb oxygen from the
atmosphere but the chlorine in the paper attacks it
and the process of destruction is thereby hastened.
The introduction of acid into ink has two purposes,
one to secure more limpidity, and the other to cause
it to penetrate the paper and in this way bind
together the constituent particles of both ink and
paper. Most of the chemical writing fluids of this
decade carry a superabundance of acid in their
composition, which in time will burn through the paper
and ultimately destroy it.
All tanno-gallate of iron inks require some vehicle
to hold their particles in a state of suspension, otherwise
there would be precipitation and such an ink
could not be used. To meet this requirement a
variety of gums are employed by manufacturers,
gum acacia being the principal one. Its purpose is
threefold--as before stated, to hold the ink particles
in suspension--to prevent the ink from flowing too
rapidly, and after drying WITHOUT blotting, to act as
an envelope to encase the now fixed ink and prevent
or interfere with its absorption of an excess of oxygen.
The longer these latter conditions obtain the longer
will the ink retain its pristineness, its durability and
permanence. The "time proved" ink-written specimens
of five hundred years or more ago which continue
to retain their original intense black color and
"glossy" appearance, do not, however, yield any evidence
of the use of vegetable gums in their composition.
Where such instances have been noticed the gloss is
invariably missing. But, where ANY gloss is present,
it was and is because of the employment of isinglass
(fish-glue) as the vehicle to hold the ancient ink
particles.
Public-domain text, read in full here on John Shaqi.
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