Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.Carvalho, David Nunes
History
Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.
Carvalho, David Nunes
Ink
A popular material for the purpose of making
chemical erasures is chlorinated lime or soda, which
becomes more active by first touching the ink mark
to be removed with a one half strength solution of
acetic acid; this hastens the liberation of chlorine
gas, THE active agent which causes the "bleaching"
to take place. Hydrogen peroxide, also a bleaching
compound, is less rapid in its action than chlorinate
of soda; the same may be said of combinations of
oxalic and sulphurous acids.
The most effective re-agent for the restoration of a
chemically "bleached" iron ink mark is the sulphide
or sulphuret of ammonia (it has several names). This
penetrating chemical blackens metals or their salts,
whether visible or not, if brought together. It must
not be used by direct contact, the best and safest
plan being to place a quantity in a small saucer, to be
set on the floor of a closed box; to fasten to the box
lid the specimen to be operated on; in this way the
restoration is due to the fumes of the chemical and a
possible danger of destruction of the specimen much
lessened, especially if the marks are very light or delicate
ones. The restoration of color under particular
conditions may also be obtained by treatment with
tannic acid, potassium ferro-cyanide (acidulated) or a
weak solution of an infusion of galls.
CHAPTER XVIII.
INK CHEMISTRY.
SOME OBSERVATIONS AS TO CHEMICAL EXAMINATION OF
INK MARKS BY ALLEN--ERASING OF INKS BY CHEMICAL
MEANS--APPROVED CHEMICAL TESTS IN THE
ASCERTAINMENT OF INK CONSTITUENTS.
A COMPILATION of the methods of Robertson,
W. Thompson (Lord Kelvin), Irvine, Wislar, Hoffman
and others, relative to the chemical examination of ink
marks, is to be found in "Allen's Commercial Organic
Analysis." Their experiments, however, date back
many years ago, a few of them before the time of the
use of the "anilines" for added color. The so-called
"alizarin" ink referred to has now become obsolete.
The following is the citation in part:
"In chemico-legal cases it is sometimes of
importance to ascertain the nature of the ink used,
to compare it with specimens of writing of known
history, and to ascertain the relative ages of the
writings. A minute inspection should first be
made with a magnifying power of about 10 diameters,
and any peculiarities of color, lustre, shade,
etc., duly noted, and where lines cross each other
which lie uppermost. The examination is often
facilitated by moistening the paper with benzine
or petroleum spirit, whereby it is rendered semi-
transparent. The use of alcohol or water is inadmissible.
Public-domain text, read in full here on John Shaqi.
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