Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.Carvalho, David Nunes
History
Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.
Carvalho, David Nunes
Ink
M. Piesse, in the Scientific American, is authority
for a method of removing ink, found on "patent"
check paper:
"Alternately wash the paper with a camel's-
hair brush dipped in a solution of cyanide of
potassium and oxalic acid; then when the ink has
disappeared wash the paper with pure water."
Inks of the tanno-gallate of iron family, whether
containing "added" color or not, can be more or less
"erased" by chlorinate of lime or soda, in the
presence of a weak acid. These chemicals do not,
however, materially affect the prussian blue inks,
which require solutions of hydrate of potash or soda.
Real indigo can be removed by chloroform, morphine
or an aniline salt (indigo and aniline both owe their
names to the same Portuguese source), which possess
the rare property of dissolving pure indigo. Such
combination, if refractory in the presence of permanganate
of potash with sulphuric acid, must be followed
by an application of sulphurous acid. In like
manner, inks composed of by-products of coal tar, can
be effectively treated, when irradicable with plain
water or soap and water.
The erasure and removal of most inks from paper
can be accomplished by the application of the chemicals
heretofore enumerated. The requirements in
this direction of some inks, however, though of rare
occurrence, are to be met by the employment of other
and particular reagents.
Many of the tests specified in the Allen citation to
determine the character of ink constituents, if made
alone are practically valueless, because the same behavior
occurs with different materials employed in the
admixture of ink. To avoid error in judgment the
operator should verify if possible by confirmatory
tests. Thus, in the one for logwood, sulphurous acid
will cause a logwood ink mark to turn yellow; mercuric
chloride, orange; tartar-emetic, red; and if the
marks are faded ones, solutions of sulphate of iron
or bichromate of potash will restore them respectively
to a violet or blue-black color.
Prussian blue, aniline blue and indigo blue are to
be tested as follows: Solution of chloride of lime, no
change of color for prussian blue; decoloration or
faint yellow for aniline blue or indigo. To discriminate
between the two latter, test with solution of
caustic soda, when decoloration or change of color
will indicate aniline blue and permanence will indicate
presence of indigo blue.
In the manufacture of the blue-black inks, a variety
of violets have been and are still employed. Among
them are aniline violet, iodine violet, madder, alkanet,
orchil and logwood.
(a) Apply chloride of lime solution: 1. No change
of color indicates alkanet. 2. Any change, one of
the other five.
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