Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.Carvalho, David Nunes
History
Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.
Carvalho, David Nunes
Ink
"Mr. John Spiller communicated to the London
Chemical News (1861) a paper on the employment
of carbon as a means of permanent record. The
imperishable nature of carbon, in its various forms
of lamp-black, ivory-black, wood-charcoal, and
graphite or black lead, holds out much greater
promise of being usefully employed in the manufacture
of a permanent writing material; since, for
this substance, in its elementary condition and at
ordinary temperatures, there exists no solvent nor
chemical reagent capable of affecting its alteration.
"The suggestion relative to the mode of applying
carbon to these purposes, which it is intended
more particularly now to enunciate, depends on
the fact of the separation of carbon from organic
compounds rich in that element, sugar, gum, etc.,
by the combined operation of heat and of chemical
reagents, such as sulphuric and phosphoric acids,
which exert a decomposing action in the same
direction; and by such means to effect the deposition
of the carbon within the pores of the
paper by a process of development to be performed
after the fluid writing ink has been to a certain
extent absorbed into its substance--a system of
formation by which a considerable amount of resistance,
both to chemical and external influences,
appears to be secured. An ink of the following
composition has been made the subject of experiment:
"Concentrated sulphuric acid,
deeply colored with indigo .......... 1 fluid ounce.
Water, .............................. 6 " "
Loaf Sugar,.......................... 1 ounce, troy.
Strong mucilage of gum-arabic
2 to 3 fluid ounces.
"Writing traced with a quill or gold pen dipped
in this ink dries to a pale blue color; but if now a
heated iron be passed over its surface, or the page
of manuscript be held near a fire, the writing will
quickly assume a jet black appearance, resulting
from the carbonization of the sugar by a warm
acid, and will have become so firmly engrafted
into the substance of the paper as to oppose considerable
difficulty to its removal or erasure by a
knife. On account of the depth to which the
written characters usually penetrate, the sheets of
paper selected for use should be of the thickest
make, and good white cartridge paper, or that
known as 'cream laid,' preferred to such as are
colored blue with ultramarine; for, in the latter
case, a bleached halo is frequently perceptible
around the outlines of the letters, indicating the
partial destruction of the coloring matter by the
lateral action of the acid.
Public-domain text, read in full here on John Shaqi.
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