Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.Carvalho, David Nunes
History
Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.
Carvalho, David Nunes
Ink
"The author stated that in 1842 he commenced
a series of experiments on writing inks, and up to
this date (1855), had manufactured 229 different
inks, and had tested the durability of writings made
with these on all kinds of paper. As the result
of his experiments be showed that the browning
and fading of inks resulted from many causes,
but in ordinary inks chiefly from the iron becoming
peroxygenated and separating as a heavy
precipitate. Many inks, therefore, when fresh made,
yielded durable writings; but when the ink became
old, the tanno-gallate of iron separated, and
the durability of the ink was destroyed. From a
numerous set of experiments the author showed
that no salt of iron and no precipitate of iron
equalled the common sulphate of iron--that is,
the commercial copperas--for the purpose of ink-
making; and that even the addition of any persalt,
such as the nitrate or chloride of iron, though
it improved the present color of the ink, deteriorated
its durability. The author failed to procure
a persistent black ink from manganese, or other
metal or metallic salt. The author exhibited a series
of eighteen inks which had either been made
with metallic iron or with which metallic iron had
been immersed, and directed attention to the fact
that though the depth and body of color seemed to
be deepened, yet in every case the durability of
writings made with such inks was so impaired that
they became brown and faded in a few months.
The most permanent ordinary inks were shown to
be composed of the best blue gall nuts with copperas
and gum, and the proportions found on experiment
to yield the most persistent black were
six parts of best blue galls to four parts of copperas.
Writings made with such an ink stood exposure
to sun and air for twelve months without
exhibiting any change of color, while those made
with inks of every other proportion or composition
had more or less of their color discharged when
similarly tested. This ink, therefore, if kept from
moulding and from depositing its tanno-gallate of
iron, would afford writings perfectly durable. It
was shown that no gall and logwood ink was equal
to the pure gall ink in so far as durability in the
writings was concerned. All such inks were exhibited
which, though durable before the addition
of logwood, faded rapidly after logwood was added
to them. Sugar was shown to have an especially
hurtful action on the durability of inks containing
logwood--indeed, on all inks. Many other plain
inks were exhibited, and their properties described
--as gallo-sumach ink, myrabolams ink, Runge's ink,
--inks in which the tanno-gallate of iron was kept
in solution by nitric, muriatic, sulphuric, and other
acids, or by oxalate of potash, chloride of lime,
etc. The myrabolams was recommended as an ink
of some promise for durability, and as the cheapest
ink it was possible to manufacture. All ordinary
inks, however, were shown to have certain drawbacks,
and the author endeavored to ascertain by
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