Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.Carvalho, David Nunes
History
Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.
Carvalho, David Nunes
Ink
4. The proportion of iron in the precipitate varies
greatly with the length of time the ink has been exposed.
At first the precipitate contains 10 per cent
of iron, but by and by a new one having only 7.5
per cent is formed, and in from forty to seventy days
we find one of 5.7 per cent. Simultaneously iron increases
in the ink (proportionate to the tannin).
5. The results show, and practice confirms, that
16 parts of iron (80 ferrous sulphate) and 100 parts of
tannin are best for ink manufacture.
The research now travelled in a direction which
accumulating experience showed to be obligatory.
Blue-black tannin ink lost color, and the reducing
nature of the tannin tended to the formation of a
highly objectionable precipitate in the ink, which
made writing anything but a pleasure. These two
faults were doubtless linked together in some way
and seemed not to exist when gallic acid was used,
for ink so made was found to precipitate only after
a long exposure, it required no free acid to keep the
precipitate in solution, and retained the indigo blue
color for a long time; alkalis did not decompose the
ink, and provided blacker and more permanent writing.
Determination of the correct proportions of
gallic acid and ferrous-sulphate was the subject of prolonged
experiments conducted on similar lines to those
already detailed. The conclusions as to precipitation
were also similar. Thirty parts of iron (150 of ferrous-
sulphate) and 100 parts of gallic acid were found to
be the most suitable proportions for ink-making. It
is advisable, however, not to discard tannin altogether,
owing to the slow blackening of the gallic acid ink,
and a little tannin gives initial blackening and body,
while it is absolutely necessary for copying ink.
Initial blackness can also be ensured by oxidizing
21 per cent of the ferrous-sulphate without adding
the extra acid necessary to the formation of a ferric
salt.
The concluding portion of his research is devoted
to the influence of sugar upon the permanence of ink,
and the results of the experiments are summed up in
the following sentences: "It would be injurious to
add 3 per cent of sugar to a tan in ink, while from
4 to 10 per cent would be quite allowable. Most
copying inks contain about 3.5 per cent of sugar--
not far from the critical amount. With gallic acid
more than 3 per cent of sugar hardly varies the precipitate,
but the importance of this point is somewhat
diminished by the fact that the presence of sugar is
by no means necessary in a writing ink. Dextrin is
a much superior substance to use. Curiously this
body rapidly precipitates a tannin ink; hence it is
useless for copying ink, but for the gallic ink it is an
excellent thickener."
Chen-Ki-Souen, "Lencre de China," by Maurice Jametel,
appeared in Paris in 1882, but as the title indicates,
it is the old "Indian" or Chinese ink that is discussed.
Public-domain text, read in full here on John Shaqi.
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