Fragments of Science: A Series of Detached Essays, Addresses, and Reviews. V. 1-2Tyndall, John
Science
Fragments of Science: A Series of Detached Essays, Addresses, and Reviews. V. 1-2
Tyndall, John
Chemistry; Physics; Science
From the illuminated bluish cloud, therefore, polarised light was
discharged, the direction of maximum polarisation being at right
angles to the illuminating beam; the plane of vibration of the
polarised light was perpendicular to the beam. [Footnote: This is
still an undecided point; but the probabilities are so much in its
favour, and it is in my opinion so much preferable to have a physical
image on which the mind can rest, that I do not hesitate to employ the
phraseology in the text.]
Thin plates of selenite or of quartz, placed between the Nicol and the
actinic cloud, displayed the colours of polarised light, these colours
being most vivid when the line of vision was at right angles to the
experimental tube. The plate of selenite usually employed was a
circle, thinnest at the centre, and augmenting uniformly in thickness
from the centre outwards. When placed in its proper position between
the Nicol and the cloud, it exhibited a system of splendidly-coloured
rings.
The cloud here referred to was the first operated upon in the manner
described. It may, however, be greatly improved upon by the choice of
proper substances, and by the application, in proper quantities, of
the substances chosen. Benzol, bisulphide of carbon, nitrite of amyl,
nitrite of butyl, iodide of allyl, iodide of isopropyl, and many other
substances may be employed. I will take the nitrite of butyl as
illustrative of the means adopted to secure the best result, with
reference to the present question.
And here it may be mentioned that a vapour, which when alone, or mixed
with air in the experimental tube, resists the action of light, or
shows but a feeble result of this action, may, when placed in
proximity with another gas or vapour, exhibit vigorous, if not violent
action. The case is similar to that of carbonic acid gas, which,
diffused in the atmosphere, resists the decomposing action of solar
light, but when placed in contiguity with chlorophyl in the leaves of
plants, has its molecules shaken asunder.
Dry air was permitted to bubble through the liquid nitrite of butyl,
until the experimental tube, which had been previously exhausted, was
filled with the mixed air and vapour. The visible action of light
upon the mixture after fifteen minutes' exposure was slight. The tube
was afterwards filled with half an atmosphere of the mixed air and
vapour, and a second half-atmosphere of air which had been permitted
to bubble through fresh commercial hydrochloric acid. On sending the
beam through this mixture, the tube, for a moment, was optically
empty. But the pause amounted only to a small fraction of a second, a
dense cloud being immediately precipitated upon the beam.
This cloud began blue, but the advance to whiteness was so rapid as
almost to justify the application of the term instantaneous. The
dense cloud, looked at perpendicularly to its axis, showed scarcely
any signs of polarisation. Looked at obliquely the polarisation was
strong.
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