Fragments of Science: A Series of Detached Essays, Addresses, and Reviews. V. 1-2Tyndall, John
Science
Fragments of Science: A Series of Detached Essays, Addresses, and Reviews. V. 1-2
Tyndall, John
Chemistry; Physics; Science
The experimental tube being again cleansed and exhausted, the mixed
air and nitrite-of-butyl vapour was permitted to enter it until the
associated mercury column was depressed 1/10 of an inch. In other
words, the air and vapour, united, exercised a pressure not exceeding
1/300th of an atmosphere. Air, passed through a solution of
hydrochloric acid, was then added, till the mercury column was
depressed three inches. The condensed beam of the electric light was
passed for some time through this mixture without revealing anything
within the tube competent to scatter the light. Soon, however, a
superbly blue cloud was formed along, the track of the beam, and it
continued blue sufficiently long to permit of its thorough
examination. The light discharged from the cloud, at right angles to
its own length, was at first perfectly polarised. It could be totally
quenched by the Nicol. By degrees the cloud became of whitish blue,
and for a time the selenite colours, obtained by looking at it
normally, were exceedingly brilliant. The direction of maximum
polarisation was distinctly at right angles to the illuminating beam.
This continued to be the case as long as the cloud maintained a
decided blue colour, and even for some time after the blue had changed
to whitish blue. But, as the light continued to act, the cloud became
coarser and whiter, particularly at its centre, where it at length
ceased to discharge polarised light in the direction of the
perpendicular, while it continued to do so at both ends.
But the cloud which had thus ceased to polarise the light emitted
normally, showed vivid selenite colours when looked at obliquely,
proving that the direction of maximum polarisation changed with the
texture of the cloud. This point shall receive further illustration
subsequently.
A blue, equally rich and more durable, was obtained by employing the
nitrite-of-butyl vapour in a still more attenuated condition. The
instance here cited is representative. In all cases, and with all
substances, the cloud formed at the commencement, when the
precipitated particles are sufficiently fine, is _blue_, and it can be
made to display a colour rivalling that of the purest Italian sky. In
all cases, moreover, this fine blue cloud polarises _perfectly_ the beam
which illuminates it, the direction of polarisation enclosing an angle
of 90° with the axis of the illuminating beam.
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