For those not understanding the above it will be as well to explain,
that on the left-hand side of the equation are placed the compounds
brought into contact, water (H_{2}O) and carbon (C), and on the right
the products of the chemical action, carbon monoxide (CO), carbonic
acid gas (CO_{2}), and hydrogen (H_{2}).
The resulting water gas contains 60% of hydrogen and 20% of carbon
monoxide, both of which are combustible gases. The proportions of the
gases evolved can be varied at will by admitting more steam or using an
excess of carbon; by this process a richer gas can be obtained—
C + H_{2}O = CO + H_{2},
and
5 H_{2}O + 3 C = 2 CO_{2} + CO + 5 H_{2}.
With 18 parts of steam and 12 parts of carbon we can obtain by the
former equation 28 parts of carbon monoxide and 2 parts of hydrogen.
This forms an extremely calorific mixture.
There are several processes for preparing water gas which give good
practical results, and the gas produced has been used in America and
Germany for lighting towns on the incandescent gas-burner system.
The Strong and Lowe processes consist of a furnace lined with
fire-bricks, and in which is placed coal or coke. When this mass of
carbon has reached a state of bright incandescence by playing upon it a
stream of air, steam is admitted at high temperature, and is decomposed
by the carbon forming oxides and liberating hydrogen. The gaseous
products pass from the furnace to a reservoir.
When the chemical action ceases, due to cooling of the carbon, the
steam is shut off and the stream of air turned on till it becomes
incandescent once more. The process of admitting steam is then repeated.
About 2½ lbs. of coke are necessary to produce 20 cubic feet of
water gas.
Analysis of the gas reveals the following parts by volume of the
constituents.
(1) Water gas produced by the Strong process:—
Hydrogen 53 volumes
Carbon monoxide 35 ”
Hydrocarbons 4 ”
Other gases 8 ”
———
100 volumes
(2) Lowe process:—
Hydrogen 30 volumes
Carbon monoxide 28 ”
Hydrocarbons 34 ”
Other gases 8 ”
———
100 volumes
It is possible to entirely get rid of the cooling effect of the steam,
by using instead a jet of air which passes up through the carbon. First
of all carbon dioxide (CO_{2}) is formed near the bottom of the mass,
but this gas passing upwards through it is reduced to carbon monoxide
(CO) by the excess of carbon, and a mixture is obtained consisting of
34 parts by volume of carbon monoxide and 65 of nitrogen. This gas has
been named after its inventor, Siemens gas.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account