Gem-Stones and Their Distinctive CharactersSmith, George Frederick Herbert
Science
Gem-Stones and Their Distinctive Characters
Smith, George Frederick Herbert
Precious stones
There is yet another remarkable phenomenon which must not be passed
over. Certain substances, of which quartz is a conspicuous example and
in this respect unique among the gem-stones, possess the remarkable
property of rotating the plane of polarization of a ray of light which
is transmitted parallel to the optic axis. If a plate of quartz be
cut at right angles to the axis and placed between crossed nicols in
white light, the field will be coloured, the hue changing on rotation
of one nicol with respect to the other. Examination in monochromatic
light shows that the field will become dark after a certain rotation of
the one nicol with respect to the other, the amount of which depends
on the thickness of the plate. If the plate be viewed in convergent
light, an interference picture is seen as illustrated on Plate III,
which is similar to, and yet differs in some important particulars
from the ordinary interference picture of a uniaxial stone. The cross
does not penetrate beyond the innermost ring and the centre of the
field is coloured in white light. If a stone shows such a picture, it
may be safely assumed to be quartz. It is interesting to note that
minerals which possess this property have a spiral arrangement of the
constituent atoms.
It has already been remarked (p. 28) that if a faceted doubly
refractive stone be rotated with one facet always in contact with the
dense glass of the refractometer the pair of shadow-edges that are
visible in the field move up or down the scale in general from or
to maximum and minimum positions. The manner in which this movement
takes place depends upon the character of the double refraction and
the position of the facet under observation with regard to the optical
symmetry of the stone. In the case of a uniaxial stone, if the facet
be perpendicular to the crystallographic axis, i.e. the direction
of single refraction, neither of the shadow-edges will move. If the
facet be parallel to that direction, one shadow-edge will move up and
coincide with the other, which remains invariable in position, and
away from it to a second critical position; the latter gives the value
of the extraordinary refractive index, and the invariable shadow-edge
corresponds to the ordinary refractive index. This phenomenon is
displayed by the table-facet of most tourmalines, because for
reasons given above (p. 11) they are as a rule cut parallel to the
crystallographic axis. In the case of facets in intermediate positions,
the shadow-edge corresponding to the extraordinary refractive index
moves, but not to coincidence with the invariable shadow-edge. The case
of a biaxial stone is more complex. If the facet be perpendicular to
one of the principal directions one shadow-edge remains invariable in
position, corresponding to one of the principal refractive indices,
whilst the other moves between the critical values corresponding
to the remaining two of the principal refractive indices. In the
Public-domain text, read in full here on John Shaqi.
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