Gem-Stones and Their Distinctive CharactersSmith, George Frederick Herbert
Science
Gem-Stones and Their Distinctive Characters
Smith, George Frederick Herbert
Precious stones
The absorptive properties of all doubly refractive coloured substances
vary more or less with the direction in which light traverses them
according to the amount of dichroism that they possess, but the
variation is not very noticeable unless the stone is highly dichroic.
If the light transmitted by a deep-coloured ruby be examined with a
spectroscope it will be found that the whole of the green portion of
the spectrum is obliterated (Fig. 31), while in the case of a sapphire
only a small portion of the red end of the spectrum is absorbed.
Alexandrite affords especial interest. In the spectrum of the light
transmitted by it, the violet and the yellow are more or less strongly
absorbed, depending upon the direction in which the rays have passed
through the stone (Fig. 31), and the transmitted light is mainly
composed of two portions—red and green. The apparent colour of the
stone depends, therefore, upon which of the two predominates. In
daylight the resultant colour is green flecked with red and orange,
the three principal absorptive tints (cf. p. 235), but in artificial
light, which is relatively stronger in the red portion of the spectrum,
the resultant colour is a raspberry-red, and there is less apparent
difference in the absorptive tints (cf. Plate XXVII, Figs. 11, 13).
[Illustration: FIG. 31.—Absorption Spectra.]
In all the spectra just considered, and in all like them, the portions
that are absorbed are wide, the passage from blackness to colour is
gradual, and the edges deliminating them are blurred. In the spectra of
certain zircons and in almandine garnet the absorbed portions, or bands
as they are called, are narrow, and, moreover, the transition from
blackness to colour is sharp and abrupt; such stones are therefore said
to display absorption-bands. Church in 1866 was the first to notice
the bands shown by zircon (Fig. 31). Sorby thought they portended the
existence of a new element, to which he gave the name jargonium, but
subsequently discovered that they were caused by the presence of a
minute trace of uranium. A yellowish-green zircon shows the phenomenon
best, and it has all the bands shown in the figure. The spectrum varies
slightly but almost imperceptibly with the direction in the stone.
Others show the bands in the yellow and green, while others show only
those in the red, and some only one of them. The bands are not confined
to stones of any particular colour, or amount of double refraction.
Again, many zircons show no bands at all, so that their absence by no
means precludes the stone from being a zircon.
Almandine is characterized by a different spectrum (Fig. 31). The band
in the yellow is the most conspicuous, and is no doubt responsible for
the purple hue of a typical almandine. The spectrum varies in strength
in different stones. Rhodolite (p. 214), a garnet lying between
almandine and pyrope, displays the same bands, and indications of them
may be detected in the spectra of pyropes of high refraction.
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