Gem-Stones and Their Distinctive CharactersSmith, George Frederick Herbert
Science
Gem-Stones and Their Distinctive Characters
Smith, George Frederick Herbert
Precious stones
By far the most convenient liquid for ordinary use is methylene
iodide, which has already been recommended for its high refraction.
It has, when pure, a density at ordinary room-temperatures of 3·324,
and it is miscible in all proportions with benzol, whose density is
O·88, or toluol, another hydrocarbon which is somewhat less volatile
than benzol, and whose density is about the same, namely, 0·86. When
fresh, methylene iodide has only a slight tinge of yellow, but it
rapidly darkens on exposure to light owing to the liberation of iodine
which is in a colloidal form and cannot be removed by filtration.
The liquid may, however, be easily cleared by shaking it up with any
substance with which the iodine combines to form an iodide removable
by filtration. Copper filings answer the purpose well, though rather
slow in action; mercury may also be used, but is not very satisfactory,
because a small amount may be dissolved and afterwards be precipitated
on to the stone under test, carrying it down to the bottom of the tube.
Caustic potash (potassium hydroxide) is also recommended; in this case
the operation should preferably be carried out in a special apparatus
which permits the clear liquid to be drawn off underneath, because
water separates out and floats on the surface. In Fig. 32 three cut
stones, a quartz (_a_), a beryl (_b_), and a tourmaline (_c_) are shown
floating in a diffusion column of methylene iodide and benzol. Although
the beryl is only slightly denser than the quartz, it floats at a
perceptibly lower level. These three species are occasionally found as
yellow stones of very similar tint.
[Illustration: FIG. 32.—Stones of different Specific Gravities floating
in a Diffusion Column of heavy Liquid.]
Various other liquids have been used or proposed for the same
purpose, of which two may be mentioned. The first of them is a
saturated solution of potassium iodide and mercuric iodide in water,
which is known after the discoverer as Sonstadt’s solution. It is a
clear mobile liquid with an amber colour, having at 12° C. a density
of 3·085; it may be mixed with water to any extent, and is easily
concentrated by heating; moreover, it is durable and not subject to
alteration of any kind; on the other hand, it is highly poisonous and
cauterizes the skin, not being checked by albumen; it also destroys
brass-ware by amalgamating the metal. The second is Klein’s solution,
a clear yellow liquid which has at 15° C. a density of 3·28. It
consists of the boro-tungstate of cadmium, of which the formula is
9WO_{3}.B_{2}O_{3}.2CdO.2H_{2}O + 16Aq, dissolved in water, with which
it may be diluted. If the salt be heated, it fuses at 75° C. in its
own water of crystallization to a yellow liquid, very mobile, with a
density of 3·55. Klein’s solution is harmless, but it cannot compare
for convenience of manipulation with methylene iodide.
Public-domain text, read in full here on John Shaqi.
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