Gem-Stones and Their Distinctive CharactersSmith, George Frederick Herbert
Science
Gem-Stones and Their Distinctive Characters
Smith, George Frederick Herbert
Precious stones
It is possible to employ a similar method for still denser stones by
having recourse to Retgers’s salt, silver-thallium nitrate. This double
salt is solid at ordinary room-temperatures, but has the remarkable
property of melting at a temperature, 75° C., which is well below the
point of fusion of either of its constituents, to a clear, mobile
yellow liquid, which is miscible in any proportion with water, and
has, when pure, a density of 4·6. The salt may be purchased, or it may
be prepared by mixing 100 grams of thallium nitrate and 64 grams of
silver nitrate, or similar proportions, in a little water, and heating
the whole over a water-bath, keeping it constantly stirred with a
glass rod until it is liquefied. The two salts must be mixed in the
correct proportions, because otherwise the mixture might form other
double salts, which do not melt at so low a temperature. A glance at
the table of specific gravities shows that Retgers’s salt may be used
for all the gem-stones with the single exception of zircon (b). There
are, however, some objections to its use. It is expensive, and, unless
kept constantly melted, it is not immediately available. It darkens on
exposure to strong sunlight like all silver salts, stains the skin a
peculiar shade of purple which is with difficulty removed, and in fact
only by abrasion of the skin, and, like all thallium compounds, is
highly poisonous.
It is convenient to have three tubes, fitted as before with stoppers
or corks, to contain the following liquids, when heated:—
(_e_) Silver-thallium nitrate, reduced to 3·5; using as indicators,
peridot or idocrase 3·40 and topaz 3·53.
(_f_) Silver-thallium nitrate, reduced to 4·0; indicators, topaz 3·53
and sapphire 4·03.
(_g_) Silver-thallium nitrate, undiluted, 4·6.
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