Gems in the Smithsonian InstitutionDesautels, Paul E.
History
Gems in the Smithsonian Institution
Desautels, Paul E.
Gems; Precious stones; Smithsonian Institution
Opal is unlike most gemstones in that its flashing color is not due to
the color of the stone itself, or even to the color of its included
impurities. Rather, it is due to the way in which tiny opal particles
are grouped during its formation. Detailed photographs taken through an
electron microscope show clearly how precious opal is deposited as
spheres that are so small they are indistinguishable under powerful
optical microscopes. These spheres are packed together in very orderly
networks, row upon row and layer upon layer, with tiny open spaces, also
in rows, between them. Masses of common opal lack this orderly internal
arrangement of spheres. White light striking the precious opal is
reflected independently by each row of spheres, much like the
reflections from a series of slats in a venetian blind. Since these rows
of spheres are spaced at distances approximately the same as the
wavelength of light, a phenomenon known as _diffraction_ occurs. The
separate reflections interfere with each other in an organized manner,
cancelling out some of the light wavelengths and reinforcing others,
producing color. The brilliant color flashes are of different hues
depending on the sizes of the spheres of opal and, therefore, the
distances between rows. To provide the best display of this optical
effect, opal is almost always cut in cabochon form rather than as
faceted stones.
[Illustration: Fire opals have rich fire; some have background
colors that vary from bright yellow through orange and red; and some
are colorless. Stones such as the ones shown here, which weigh 7,
11, and 22 carats, have made Querétaro, Mexico, famous as their
source. (Actual size.)]
[Illustration: This rare 34-carat opal from Brazil resembles closely
the opals found in Australia. (Actual size.)]
Common opal, which shows milky opalescence, does not exhibit color
flashes, and it is not used as a gemstone. Each of the common
varieties—such as hyalite, cacholong, and hydrophane—has its own
slightly different set of characteristics, but only precious opal, with
its dazzling color display, is important for gem purposes. To take full
advantage of the small amounts of gem material available, or to bring
out its color better, _precious_ opal is often cut as thin pieces and
mounted as doublets on some other backing. Also, the seams in rock
sometimes are cut so that the thin layer is exposed on a thicker backing
of the adjoining rock. Precious opal, or gem opal, is classified as
_white opal_ when the color flashes are in a whitish or light
background, _black opal_ when the background material is gray,
blue-gray, or black, and _fire opal_ when the background is more
translucent and red, reddish orange, or reddish yellow.
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