The best laboratory method of securing free chlorine is to heat in a
water bath a mixture of hydrochloric acid and manganese dioxide, a
compound containing one part of manganese and two parts of oxygen. The
heat causes the manganese dioxide to give up its oxygen, which
immediately combines with the hydrogen of the hydrochloric acid and
forms water. The manganese itself combines with part of the chlorine
originally in the acid, but not with all. There is thus some free
chlorine left over from the acid, and this passes off as a gas and can
be collected, as in Figure 158. Free chlorine is heavier than air, and
hence when it leaves the exit tube it settles at the bottom of the
jar, displacing the air, and finally filling the bottle.
Chlorine is a very active substance and combines readily with most
substances, but especially with hydrogen; if chlorine comes in contact
with steam, it abstracts the hydrogen and unites with it to form
hydrochloric acid, but it leaves the oxygen free and uncombined. This
tendency of chlorine to combine with hydrogen makes it valuable as a
bleaching agent. In order to test the efficiency of chlorine as a
bleaching agent, drop a wet piece of colored gingham or calico into
the bottle of chlorine, and notice the rapid disappearance of color
from the sample. If unbleached muslin is used, the moist strip loses
its natural yellowish hue and becomes a clear, pure white. The
explanation of the bleaching power of chlorine is that the chlorine
combines with the hydrogen of the water and sets oxygen free; the
uncombined free oxygen oxidizes the coloring matter in the cloth and
destroys it.
Chlorine has no effect on dry material, as may be seen if we put dry
gingham into the jar; in this case there is no water to furnish
hydrogen for combination with the chlorine, and no oxygen to be set
free.
Public-domain text, read in full here on John Shaqi.
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