219. Bleaching Powder. Chlorine gas has a very injurious effect on
the human body, and hence cannot be used directly as a bleaching
agent. It attacks the mucous membrane of the nose and lungs, and
produces the effect of a severe cold or catarrh, and when inhaled,
causes death. But certain compounds of chlorine are harmless, and can
be used instead of chlorine for destroying either natural or
artificial dyes. One of these compounds, namely, chloride of lime, is
the almost universal bleaching agent of commerce. It comes in the form
of powder, which can be dissolved in water to form the bleaching
solution in which the colored fabrics are immersed. But fabrics
immersed in a bleaching powder solution do not lose their color as
would naturally be expected. The reason for this is that the chlorine
gas is not free to do its work, but is restricted by its combination
with the other substances. By experiment it has been found that the
addition to the bleaching solution of an acid, such as vinegar or
lemon juice or sulphuric acid, causes the liberation of the chlorine.
The chlorine thus set free reacts with the water and liberates oxygen;
this in turn destroys the coloring matter in the fibers, and
transforms the material into a bleached product.
The acid used to liberate the chlorine from the bleaching powder, and
the chlorine also, rot materials with which they remain in contact for
any length of time. For this reason, fabrics should be removed from
the bleaching solution as soon as possible, and should then be rinsed
in some solution, such as ammonia, which is capable of neutralizing
the harmful substances; finally the fabric should be thoroughly rinsed
in water in order that all foreign matter may be removed. The reason
home bleaching is so seldom satisfactory is that most amateurs fail to
realize the necessity of immediate neutralization and rinsing, and
allow the fabric to remain too long in the bleaching solution, and
allow it to dry with traces of the bleaching substances present in the
fibers. Material treated in this way is thoroughly bleached, but is at
the same time rotten and worthless. Chloride of lime is frequently
used in laundry work; the clothes are whiter than when cleaned with
soap and simple washing powders, but they soon wear out unless the
precaution has been taken to add an "antichlor" or neutralizer to the
bleaching solution.
220. Commercial Bleaching. In commercial bleaching the material to
be bleached is first moistened with a very weak solution of sulphuric
acid or hydrochloric acid, and is then immersed in the bleaching
powder solution. As the moist material is drawn through the bleaching
solution, the acid on the fabric acts upon the solution and releases
chlorine. The chlorine liberates oxygen from the water. The oxygen in
turn attacks the coloring matter and destroys it.
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