[Illustration: FIG. 159.--The material to be bleached is drawn through
an acid _a_, then through a bleaching solution _b_, and finally
through a neutralizing solution _c_.]
The bleached material is then immersed in a neutralizing bath and is
finally rinsed thoroughly in water. Strips of cotton or linen many
miles long are drawn by machinery into and out of the various
solutions (Fig. 159), are then passed over pressing rollers, and
emerge snow white, ready to be dyed or to be used as white fabric.
221. Wool and Silk Bleaching. Animal fibers like silk, wool, and
feathers, and some vegetable fibers like straw, cannot be bleached by
means of chlorine, because it attacks not only the coloring matter but
the fiber itself, and leaves it shrunken and inferior. Cotton and
linen fibers, apart from the small amount of coloring matter present
in them, contain nothing but carbon, oxygen, and hydrogen, while
animal fibers contain in addition to these elements some compounds of
nitrogen. The presence of these nitrogen compounds influences the
action of the chlorine and produces unsatisfactory results. For animal
fibers it is therefore necessary to discard chlorine as a bleaching
agent, and to substitute a substance which will have a less disastrous
action upon the fibers. Such a substance is to be had in sulphurous
acid. When sulphur burns, as in a match, it gives off disagreeable
fumes, and if these are made to bubble into a vessel containing water,
they dissolve and form with the water a substance known as sulphurous
acid. That this solution has bleaching properties is shown by the fact
that a colored cloth dipped into it loses its color, and unbleached
fabrics immersed in it are whitened. The harmless nature of sulphurous
acid makes it very desirable as a bleaching agent, especially in the
home.
Silk, lace, and wool when bleached with chlorine become hard and
brittle, but when whitened with sulphurous acid, they retain their
natural characteristics.
This mild form of a bleaching substance has been put to uses which are
now prohibited by the pure food laws. In some canneries common corn is
whitened with sulphurous acid, and is then sold under false
representations. Cherries are sometimes bleached and then colored with
the bright shades which under natural conditions indicate freshness.
Bleaching with chlorine is permanent, the dyestuff being destroyed by
the chlorine; but bleaching with sulphurous acid is temporary, because
the milder bleach does not actually destroy the dyestuff, but merely
modifies it, and in time the natural yellow color of straw, cotton,
and linen reappears. The yellowing of straw hats during the summer is
familiar to everyone; the straw is merely resuming its natural color
which had been modified by the sulphurous acid solution applied to the
straw when woven.
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