282. Experiments which grew out of the Voltaic Cell. Since chemical
action on the zinc is the source of the current, it would seem
reasonable to expect a current if the cell consisted of two zinc
plates instead of one zinc plate and one copper plate. But when the
copper strip is replaced by a zinc strip so that the cell consists of
two similar plates, no current flows between them. In this case,
chemical action is expended in heat rather than in the production of
electricity and the liquid becomes hot. But if carbon and zinc are
used, a current is again produced, the zinc dissolving away as before,
and bubbles collecting on the carbon plate. By experiment it has been
found that many different metals may be employed in the construction
of an electric cell; for example, current may be obtained from a cell
made with a zinc plate and a platinum plate, or from a cell made with
a lead plate and a copper plate. Then, too, some other chemical, such
as bichromate of potassium, or ammonium chloride, may be used instead
of dilute sulphuric acid.
Almost any two different substances will, under proper conditions,
give a current, but the strength of the current is in some cases so
weak as to be worthless for practical use, such as telephoning, or
ringing a door bell. What is wanted is a strong, steady current, and
our choice of material is limited to the substances which will give
this result. Zinc and lead can be used, but the current resulting is
weak and feeble, and for general use zinc and carbon are the most
satisfactory.
283. Electrical Terms. The plates or strips used in making an
electric cell are called electrodes; the zinc is called the negative
electrode (-), and the carbon the positive electrode (+); the current
is considered to flow through the wire from the + to the-electrode. As
a rule, each electrode has attached to it a binding post to which
wires can be quickly fastened.
The power that causes the current is called the electromotive force,
and the value of the electromotive force, generally written E.M.F., of
a cell depends upon the materials used.
When the cell consists of copper, zinc, and dilute sulphuric acid, the
electromotive force has a definite value which is always the same no
matter what the size or shape of the cell. But the E.M.F. has a
decidedly different value in a cell composed of iron, copper, and
chromic acid. Each combination of material has its own specific
electromotive force.
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