284. The Disadvantage of a Simple Cell. When the poles of a simple
voltaic cell are connected by a wire, the current thus produced
slowly diminishes in strength and, after a short time, becomes feeble.
Examination of the cell shows that the copper plate is covered with
hydrogen bubbles. If, however, these bubbles are completely brushed
away by means of a rod or stick, the current strength increases, but
as the bubbles again gather on the + electrode the current strength
diminishes, and when the bubbles form a thick film on the copper
plate, the current is too weak to be of any practical value. The film
of bubbles weakens the current because it practically substitutes a
hydrogen plate for a copper plate, and we saw in Section 282 that a
change in any one of the materials of which a cell is composed changes
the current.
This weakening of the current can be reduced mechanically by brushing
away the bubbles as soon as they are formed; or chemically, by
surrounding the copper plate with a substance which will combine with
the free hydrogen and prevent it from passing onward to the copper
plate.
[Illustration: FIG 198. The gravity cell.]
In practically all cells, the chemical method is used in preference to
the mechanical one. The numerous types of cells in daily use differ
chiefly in the devices employed for preventing the formation of
hydrogen bubbles, or for disposing of them when formed. One of the
best-known cells in which weakening of the current is prevented by
chemical means is the so-called gravity cell.
285. The Gravity Cell. A large, irregular copper electrode is placed
in the bottom of a jar (Fig. 198), and completely covered with a
saturated solution of copper sulphate. Then a large, irregular zinc
electrode is suspended from the top of the jar, and is completely
covered with dilute sulphuric acid which does not mix with the copper
sulphate, but floats on the top of it like oil on water. The hydrogen
formed by the chemical action of the dilute sulphuric acid on the zinc
moves toward the copper electrode, as in the simple voltaic cell. It
does not reach the electrode, however, because, when it comes in
contact with the copper sulphate, it changes places with the copper
there, setting it free, but itself entering into the solution. The
copper freed from the copper sulphate solution travels to the copper
electrode, and is deposited on it in a clean, bright layer. Instead of
a deposit of hydrogen there is a deposit of copper, and falling off in
current is prevented.
The gravity cell is cheap, easy to construct, and of constant
strength, and is in almost universal use in telegraphic work.
Practically all small railroad stations and local telegraph offices
use these cells.
[Illustration: FIG. 199.--A dry cell.]
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