Getting Gold: A Gold-Mining Handbook for Practical MenJohnson, J. C. F. (Joseph Colin Francis)
History
Getting Gold: A Gold-Mining Handbook for Practical Men
Johnson, J. C. F. (Joseph Colin Francis)
Gold mines and mining
Mr. Skey also showed by very carefully conducted experiments that the
metallic sulphides are not only better conductors of electricity than
has hitherto been supposed, but that when paired they were capable of
exhibiting strong electro-motive power. Thus, if galena and zinc blende
in acid solutions be connected in the usual manner by a voltaic pair,
sulphuretted hydrogen is evolved from the surface of the former, and a
current generated which is sufficient to reduce gold, silver or copper
from their solutions in coherent electro-plate films. The attributing of
this property of generating voltaic currents, hitherto supposed to be
almost peculiar to metals, to the common sulphides found in
metalliferous veins, led Mr. Skey to speculate how far the currents
discovered to exist in such veins by Mr. E. F. Fox might be produced by
the gradual oxidation of mixed sulphides, and his conclusion is that
veins containing bands of different metallic sulphides, bounded by
continuing walls, and saturated with mineral waters, may constitute
under some circumstances a large voltaic battery competent to produce
electro-deposition of metals, and that the order of the deposit of these
mineral lodes will be found to bear a definite relation to the order in
which the sulphides rank in the table of their electro-motive power.
These researches may lead to some clearer comprehension of the law which
regulates the distribution of auriferous veins, and may explain why in
some cases the metal should be nearly pure, while in others it is so
largely alloyed with silver.
The following extract was lately clipped from a mining paper. If true,
the experiment is interesting:--
“An American scientist has just concluded a very interesting
and suggestive experiment. He took a crushed sample of rich ore
from Cripple Creek, which carried 1,100 ozs. of gold per ton, and
digested it in a very weak solution of sodium chloride and sulphate
of iron, making the solution correspond as near as practicable to
the waters found in Nature. The ore was kept in a place having a
temperature little less than boiling water for six weeks, when all
the gold was dissolved, except what would be equal to one ounce
per ton. A few small crystals of pyrite were then placed in the
bottle of solution, and the gold began immediately to precipitate
on them. It was noticeable, however, that the pyrite crystals which
were free from zinc, galena, or other extraneous matter received no
gold precipitate. Those which had such foreign associations were
beautifully covered with fine gold crystals.”
Experimenting in a somewhat similar direction about eight years ago, I
found that the West Australian mine water, mentioned on page 85, with
the addition of an acid, was a solvent of gold. The idea of boiling it
did not occur to me, as the action was fairly rapid in cold water.
Public-domain text, read in full here on John Shaqi.
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