Glass, Merret tells us, is ‘a concrete of salt and sand or stones.’
This, in modern scientific language, we should express by saying that
it is a combination of silica with an alkali. But these substances
alone are not enough. You cannot make a glass fit for practical use
from a pure quartz sand with the addition of nothing else than a salt
of potash or soda. Such a glass—a simple alkaline silicate—would
indeed be transparent, but it would be difficult to work and very
fragile. In all cases there is need of a second base, and this, to
speak generally, should be either lime or oxide of lead. The latter
base we may for the present neglect; speaking generally, it is the
presence of lime that gives the working qualities and the requisite
toughness. These, then, are the essential materials for the preparation
of glass. Other substances may be present; alumina, for example, or one
or other of the oxides of iron, but as a rule the presence of these
latter bases is not desired—the glass would be better without them.
Putting aside, then, for the present the glass in which lead is a
constituent, as well as that in which the soda is replaced by potash,
it is remarkable how little difference of composition we find in
examples of glass of the most divergent origin. Let us compare the
composition of a Roman ‘lachrymatory’ with that of a piece of modern
English plate-glass. In a hundred parts we find—
Silica. Soda. Lime. Iron Oxide. Alumina.
Roman lachrymatory 71·5 16·5 8 1 2
English Plate-glass 72 17 6 2 2
These examples are indeed two extreme terms of a long but continuous
series. A sample of Saracenic glass of the fourteenth or of Venetian
glass of the sixteenth century, would yield on analysis much the same
result.[1]
This, then, may be regarded as the normal composition of such glass as
I shall have to deal with in this history. The main question has
generally been—How can the sand or silica, the premier element in
glass, be best converted into a substance which shall in external
aspect resemble as closely as possible the native rock crystal (itself
pure silica), but which at the same time shall be not only fusible, but
after fusing pass on cooling through a plastic condition when it may be
expanded into a vesicle and otherwise worked up into various shapes?
Long practical experience has shown that this can be best effected by
adding to the sand materials containing both soda and lime, and as far
as possible nothing beyond these bases. A glass thus compounded we may
take as our normal type, but, as I have said, the soda may in certain
cases be replaced by potash and the lime by lead oxide.
Public-domain text, read in full here on John Shaqi.
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