As to the apparent irregularity in the progress of the superficial
decay, it would seem that, apart from differences in the chemical
composition of the glass, much depends upon the preservation of the
original smooth ‘epidermis.’ Once this is impaired, whether by
accidental scratches or by the growth of fungus or lichen, the carbonic
acid or the ammonia salts contained in the air or soil find, in the
presence of moisture, a secure lodgment, and the work of decay proceeds
rapidly. Thus in the case of the little flasks of primitive glass of
which I shall have to speak in the next chapter, in one example it may
be found that the smooth skin of the glass has for more than three
thousand years remained absolutely intact, while in another specimen
from a neighbouring tomb the glass not only on the surface, but far
into the interior, has taken on a talc-like or porcelainous
consistency, and the brilliant colours have for the most part
disappeared.
There is no need to enter into the details of the chemical processes
involved in this process of decay. Suffice to say that the action is
one of the same nature as that which has played so important a part in
the geological changes of the earth’s surface, especially in the
disintegration of the granitic rocks. It depends upon the power
possessed by carbonic acid, in the presence of moisture, of decomposing
the silicates of the alkalis. The soluble carbonate of soda or of
potash thus formed is then quickly washed out from the surface of the
glass. There remains, in the form either of iridescent scales or of an
opaque pearly crust, a layer consisting not perhaps of pure silica, but
of an acid silicate of lime, alumina, or lead as the case may be.
Now a piece of clear glass may appear to the eye to be devoid of
internal structure. But the ‘metal’ has, we know, in every case been
subjected during the manufacture to a complicated series of involutions
and doublings, to say nothing of the subsequent inflation if the glass
has been subjected to a blowing process. When decay sets in—something
similar may at times be seen in the case of a piece of wrought
iron—this complicated formation is in part revealed, for it is evident
that upon it the lines taken by the decay are in a measure dependent.
On blown glass especially, the disintegration of the surface tends to
result in a scaly formation resembling that of the shell of an oyster.
As a result of the decomposition of light in its passage through these
fine superficial films, and of the partial reflection from the back of
the scales at various depths, we get those unsurpassed iridescent
effects that we associate above all with the glass of the Romans. That
these brilliant hues are dependent entirely upon the physical structure
is well shown by the total disappearance of the colours when the
surface of a piece of iridescent glass is moistened, as well as by
their reappearance when the glass is again dried.
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