Glass can be toughened to an extent which is surprising. Bastie’s
process consists of plunging the finished glass article whilst hot into
a bath of boiling oil, which toughens the glass so much as to make it
extremely hard and resistant to shocks, losing most of its brittle
nature. Strong plates of glass are produced by a process of toughening
under pressure. These plates of glass are used for ship porthole lights
and in positions where great strength is required. Toughened or hardened
glass is of great value in the production of miner’s lamp glasses and
steam-gauge tubing. Glass, when hardened, is difficult to cut even with
the diamond, and difficulty is experienced in finding suitable means to
cut it into shapes to suit commercial requirements.
“_Prince Rupert drops_,” or tears, exhibit the state in which unannealed
glass physically exists. These are made as a curiosity by dropping a
small quantity of hot metal from the gathering-iron into a bath of water
and then taking the pear-shaped drops out quickly. These pear-shaped
drops of glass will stand a hard blow on the head or thicker portion
without breaking, but, if the tail is pinched off or broken, the whole
mass crumbles and falls to powder. This well illustrates the latent
stresses or strains apparently in a state of tension and thrust within
the structure of unannealed glass.
Glass is not a good conductor of heat. This accounts for the necessity
of slow cooling or annealing glassware, and also applies when re-heating
glass, which must be done slowly and evenly to allow time for the
conduction of the heat through the mass gradually. Glass is a
non-conductor of electricity, and is used to a considerable extent in
the electrical trades for insulation purposes. Most glasses are attacked
slightly, but not readily, by water and dilute mineral acids. Continued
exposure to a moist, humid atmosphere causes slight superficial
decomposition, according to the stability and chemical composition of
the glass. Old antique specimens of glass show the superficial
decomposition caused by long continuous exposure to atmospheric
moisture. Many antique specimens have been known to collapse instantly
upon being unearthed. The first change in antique glass is exhibited by
a slight iridescence forming on the surface, gradually increasing
towards opacity afterward disintegration sets in, until it finally
collapses or crumbles to powder. Glasses high in lead are readily
attacked by the acid vapours met with in the atmosphere, but the harder
soda-lime glasses are more resistant. An excess of boric acid, soda, or
potash also renders glass subject to disintegration and decay.
Hydrofluoric acid attacks all silicate glasses, liberating silicon
fluoride. Use is made of this acid reaction in decorating glasswares in
“Etching,” by exposing the surface of glass to the fumes of hydrofluoric
acid gas in some form.
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