Glasses containing lead oxide as an ingredient are subject to reduction
when exposed to flames of a carbonaceous nature. The carbon partially
reduces the lead oxide to its metallic state, forming a black deposit.
On this account, lead glasses cannot be used in blow-pipe working with
the ease with which soda-lime glasses can be worked, without reduction
taking place. English crystal glass, which contains a high percentage of
lead, is usually melted in hooded or covered pots to prevent the
carbonaceous flames of the furnace reducing the lead and otherwise
destroying the clearness of the glassware. Soda-lime glass and others
without the presence of lead can be melted in open pots without any fear
of reduction. Modern gas-fired recuperative furnaces, in which more
complete combustion of the carbon takes place, can now be used for
melting lead glasses in open pots, thus presenting a great saving in the
fuel required to melt and produce such glass, besides permitting the use
of a cheaper form of pot. This cannot be done with the ordinary English
coal-fired furnaces.
Advantage is taken of the reducing action of the coal-gas flame when
producing lustre and iridescent glassware. A small proportion of easily
reducible metal, such as silver or bismuth, is introduced into the glass
and first melted under oxidising conditions. It is then reduced in
after-working by flaming, which deposits the metal in a thin sheen upon
the surface of the glass, where it comes in contact with the reducing
flames. An example of this effect is shown in Tiffany lustre ware, in
which silver chloride is used and reduced within the glass, giving a
pretty coloured iridescence on the surface, due to the reflection of
light from the particles of metal deposited under the surface.
“Aventurine” is a form of glass in which copper and iron oxides are
introduced under reducing conditions during melting. The glass is then
allowed to cool slowly. The metallic copper tends to separate out in
small spangled crystals, which give a pretty sparkling effect. The use
of strong reducing agents with very slow annealing is necessary to
produce this effect. Copper and gold ruby-coloured glass presents other
instances of partial precipitation of the metal by reduction within the
glass. According to the extent of reduction, the glass ranges in colour
from yellow, ruby, to brown.
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