To subdue or neutralise this objectionable tint in the glass, the glass
maker uses certain metallic oxides which give delicate counter-tints.
Only those glasses which are made from the purest materials can be
decolorized to become sufficiently clear to use in making the best table
glassware. In optical glassware, where the use of manganese is not
permissible, the greatest care has to be taken in the selection and
testing of the materials to be used. If manganese oxide be used in
making optical glass, although the eye may not be sensitive enough to
observe the actual color absorption, glass is produced in which the
solar rays are obstructed, and much less light is transmitted by the
glass when used as an optical lens or prism. Therefore the optician
avails himself of those glasses which have not been decolorized as being
more satisfactory for his purpose, as more light is transmitted by such
glasses.
Apart from the pale sea-green tint given to glass by the presence of
small traces of iron, certain of the silicates themselves produce
natural colors. The soda silicate present in soda-lime metal tends to
give a pale bluish-green tint when viewed through any thickness of
glass. The lead silicate has a yellowish hue. Each of these influences
has to be counteracted if clear crystal glass is desired. The
decolorization of glass by manganese dioxide depends upon the purple
tint it gives to glass. This purple color, being complementary to the
pale green color given by the presence of iron, serves and acts as a
counter-tint, and by the absorption of the green light, a less
perceptible coloring is produced. In the case of the decolorization of
glass, we get the red and blue of the purple subduing the blue and
yellow or green tint given by the iron. But certain other factors are
necessary. The purple color from manganese oxide is given only to glass
in the presence of oxidizing agents; and the absence of sufficient
oxidising agents in the glass batch, the purple manganese colour is
unstable and its action as a counter-tint is lost. Therefore, the glass
maker uses strong oxidising agents in his glass mixtures for crystal
effects, usually in the form of potassium nitrate and red lead, which
liberate oxygen. Whilst undergoing decomposition in the glass melt, the
presence of this free oxygen keeps the manganese used in a higher state
of oxidation, and gives the necessary purple coloration. It is also
evident that, if the glass melting in the pot is kept at a high
temperature for any considerable length of time, this period of
oxidation cannot last, and, after all the free oxygen gas has been
evolved, any further heating tends to turn the glass greenish again or
of poor colour, by the conversion of the manganese into the lower state
of oxidation in which the purple colour is not evident. If by chance the
glass maker has added too much manganese to the glass, and the purple
colour becomes too evident, he resorts to the use of a small amount of
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