The manufacture of optical glass forms a very important section of the
glass industry, and presents some of the most difficult problems the
glass maker has to deal with. It is in this section of the glass trade
that applied physical and chemical science becomes of the utmost
importance to the manufacturer. The production of optical glass is
impeded by any defects which become evident in the structure of glass
when examined under a polariscope. The presence of any striae, seeds, or
stresses within the structure of the glass disqualifies it for any
important optical work. It is a difficult matter to get pieces of
optical glass only a few inches in diameter of the right optical
constant and refractive index that are homogeneous enough to allow of
the light rays passing without some dispersion when set up for use. It
becomes necessary, therefore, to achromatise one glass with another in
the form of doublets to correct aberration. A high degree of
transparency and durability is necessary in all optical glasses.
The persistent evidence of stresses developed in the solidification of
the glass upon cooling, even when the glass is slowly and carefully
annealed, is a most difficult factor to deal with. In annealing optical
glass, the various temperatures and time periods have to be delicately
adjusted and controlled, or big losses result. Even then many efforts
may be made before a suitable piece of glass is obtained, and the costs
keep accumulating with each attempt, and some idea of the amount of
labour involved in the undertaking to produce optical glass at once
becomes evident. The use of decolorizers and impure materials is not
permissible, on account of the absorption and consequent resistance to
the passage of light rays. The annealing, instead of occupying one or
two days, is sometimes extended over a course of ten or fifteen days, in
order gradually to relieve any stress present. The pots in which the
glass is melted may only once be used, as the glass is usually allowed
to cool down gradually and undergo the process of annealing within the
pot.
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