By the “colour” of a glass is generally understood the tint or colour
which is observed when it is viewed, in comparatively thin slices, by
transmitted light; the actual colour is thus a property, not so much of
the kind or variety of glass as of each individual piece, since thick
pieces out of the same melting will show a different tint from that
seen in thinner pieces. As we have already pointed out, such glasses as
sheet or plate, which appear practically colourless when viewed in the
ordinary way, show a very decided green colour when viewed through a
considerable thickness. In the same way, a very thin layer of the glass
known as “flashing ruby” shows a brilliant red tint, but a thickness of
one-sixteenth of an inch is sufficient to render the glass practically
opaque, giving it a black appearance by both transmitted and reflected
light. Again, cobalt blue glass, when examined with a spectroscope in
thin layers, is found to transmit a notable proportion of red rays,
but thicker pieces entirely suppress these rays. These phenomena will
be readily understood when we recollect that colour in a transparent
medium arises from the fact that the medium has different absorbing
powers for light of different colours. All transparent substances,
and certainly glass, are only _partially_ transparent: all light
waves passing through such a substance are gradually absorbed, and
the extent to which they are absorbed differs according to the length
of these waves. It always happens that for some special wave-lengths
the substance has the power of absorbing the energy of the entering
waves and converting it into heat-vibrations of its own molecules or
atoms. In the most transparent and colourless glasses this process, so
far as the waves of ordinary light are concerned, only goes on to a
negligibly slight extent; if, however, we extend our view beyond the
range of ordinary visible light, and consider the region of shorter
waves that lies in the spectrum beyond the violet, we find that
ordinary colourless glass becomes strongly absorbent; thus to waves
of about half the length of those which produce upon our eyes the
impression of yellow light, ordinary glass is as opaque as is a piece
of metal to white light. In this wider sense, then, we may fairly say
that all glasses are coloured--_i.e._, all have a power of selective
absorption; but in the case of those which are nearly colourless in
the ordinary sense, this absorption takes place only for waves which
are either decidedly shorter or decidedly longer than those to which
our eyes are sensitive. Those glasses which appear coloured in the
ordinary sense, on the other hand, owe this property to the fact that
the power of absorption for light-waves extends into the region of the
visible spectrum; thus a blue or violet glass is practically opaque to
red rays, while a red glass is opaque to blue, green or violet rays.
This statement may be verified in a striking manner by holding over one
Public-domain text, read in full here on John Shaqi.
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