another a piece of deep blue or green glass and a similar piece of ruby
glass--the combination will be found to be very nearly opaque even when
each glass by itself is practically transparent.
The question which now naturally presents itself to us is, what is
the essential difference between, for instance, a piece of red glass
and a piece of “white” glass that confers upon the former the power
of absorbing blue light? A perfectly complete and satisfactory answer
to this question is not, in the writer’s opinion, available in the
present state of our knowledge, but to a certain extent the difference
between the two kinds of glass can be explained. The difference is
_produced_, in the first instance by introducing into the colourless
glass some additional chemical element or elements, the substances
in question being generally known as “colouring oxides,” although
they are by no means always introduced in the form of oxides, and are
frequently present in the glass in entirely different forms. To a
certain extent the colour of the glass may be ascribed to a definite
“colouring” property of the chemical elements concerned; thus most
of the chemical compounds of such elements as nickel, cobalt, iron,
manganese and copper are more or less deeply coloured substances,
and it would seem as if the atoms or “ions” of these elements had
the specific power of absorbing certain varieties of light-waves
while not materially affecting others. But this specific “colouring”
property is not so easily explained when we recollect that the colours
of iron compounds, for example, may be green or red according to the
state of combination in which that element is present, and that iron
has also the power of imparting either a green or a yellow colour to
glass according to circumstances. The detailed discussion of these
questions, however, lies outside our present scope, and we must
confine ourselves to the broad statement that colouring substance in
glass may be roughly divided into two kinds or groups; the first
and probably the largest group are those bodies which occur in glass
in true solution, the element itself being present in the combined
state as a silicate or other such compound (borate, phosphate, etc.)
which is soluble in the glass. In this class, the colouring effect
upon the glass is specifically that of the element introduced, and is
brought about in the same way as the colouring of water when a coloured
salt--such as copper sulphate--is dissolved in it. The second class of
colouring substances, however, behave in a different manner; they are
probably present in the glass in a state of extremely fine division,
and held not in true solution, but really in a sort of mechanical
suspension that approximates to the condition of what is known as a
“colloidal solution.” The point which is known beyond doubt, thanks
to the researches of Siedentopf and Szigmondi on ultra-microscopical
particles, is that in certain coloured glasses, of which ruby glass is
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