_Gold_ is introduced into glass for the production of brilliant ruby
tints; its behaviour is very similar to that of copper, except that
the noble metal has a great tendency to return to the metallic state
without the aid of reducing agents. No addition of tin is therefore
required, but the rate of cooling, etc., must be properly regulated,
since rapidly cooled glass containing gold shows no special colour,
the rich ruby tint being only developed when the glass is re-heated
and cooled slowly. The colouring effect of gold is undoubtedly more
regular and uniform than that of copper, and it is accordingly possible
to obtain much lighter shades of red with the aid of the noble metal.
“Gold ruby” can therefore be obtained of a tint light enough to be used
in sheets of ordinary thickness, and the process of “flashing” is not
essential.
The elements of the second group, such as magnesium, calcium,
strontium, barium, zinc and cadmium, exert no strong specific colouring
action on glass, with perhaps the exception of cadmium, and that
element only does so to any considerable extent in combination with
sulphur, sulphide of cadmium having the power of producing rich yellow
colours in glass. The sulphur compounds of barium also readily produce
deep green and yellow colours, and the formation of these tints is,
indeed, very difficult to avoid in the case of glasses containing much
barium. A colouring effect has sometimes been ascribed to zinc, but
this is not in accordance with facts.
Of the elements of the third group, only boron and aluminium are ever
found in glass in any notable quantity. Boron is present in the form of
boric acid or borates, and as such produces no colouring effect, nor
does there seem to be any tendency for the separation of free boron.
The compounds of aluminium also possess no colouring effect, although
certain compounds of this element are utilised for imparting a white
opacity to glass for certain purposes--such glass being known as “opal.”
Public-domain text, read in full here on John Shaqi.
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