_Copper_, as would be anticipated from the deep colour of most of
its compounds, produces powerful colouring effects on glass. Cupric
silicates produce intense green, to greenish-blue tints. Copper,
either as metal or oxide, added to glass in the ordinary way, always
produces the green colour; but when the full oxidation of the copper is
prevented by the presence of a reducing body, and the glass is cooled
slowly, or is exposed to repeated heating followed by slow cooling,
an intense ruby coloration is produced. In practice this colour is
produced by introducing tin as well as copper into the mixture, and
so regulating the conditions of melting as to favour reduction rather
than oxidation of the copper. Under these circumstances the copper is
left in the glass in a finely divided and evenly suspended state; if
exactly the right state of division and suspension is arrived at, a
beautiful red tint is the result, although the coloration of the glass
is so intense that it can only be employed in very thin sheets, being
“flashed” upon the surface of colourless glass to give it the necessary
strength and thickness for practical use. It is further very easy to
slightly alter the arrangement of the copper in the glass, with the
result of producing an opaque, streaky substance resembling sealing-wax
in colour and appearance, this product being, of course, useless from
the glass-maker’s point of view. Finally, by exceedingly slow cooling,
and under other favouring conditions which are not really understood,
the particles of suspended colouring-material--be it metallic copper or
cuprous oxide--grow in size and attain visible dimensions, appearing as
minute shimmering flakes, thus producing the beautiful substance known
as “aventurine.”
_Silver_ is never introduced into glass mixtures, the reason being that
it is so readily reduced to the metallic state from all its compounds
that it cannot be retained in the glass except in a finely-divided
form, causing the glass to assume a black, metallic appearance
resembling the stains produced by the reduction of lead in flint
glasses. On the other hand, silver yields a beautiful yellow colour
when applied to glass as a surface stain, and it is widely used for
that purpose.
Public-domain text, read in full here on John Shaqi.
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