_Phosphorus_ occurs in some few glasses in the form of phosphoric
acid, and this substance, as such, has no colouring effect. Calcium
phosphate, however, is sometimes added to glasses for the purpose of
producing opalescence. Its action in this respect is probably similar
to that of tin oxide and aluminium fluoride, these substances all
remaining undissolved in the glass in the form of minute particles in a
finely divided and suspended state.
_Arsenic_ does not exert a colouring effect on glass, and owing to its
volatile nature it can only be retained in glass in small quantities
and under special conditions. A “decolourising” action is sometimes
ascribed to arsenic, but if this action really exists it can only be
ascribed to the fact that arsenic compounds are capable of acting as
carriers of oxygen, and their presence thus tends to facilitate the
oxidation of impurities contained in the glass. A further reference
to this subject will be found below in reference to the compounds of
manganese.
_Antimony_, although frequently added to special glass mixtures, does
not appear to produce any very powerful effects, except possibly
in the direction of producing white opacity if present in large
proportions. The sulphide of antimony, however, exerts a colouring
influence, although its volatile and unstable character renders the
effects uncertain.
_Vanadium_, owing to its rarity, is probably never added to glass
mixtures for colouring purposes, although it is capable of producing
vivid yellow and greenish tints when present even in minute
proportions. On the other hand, vanadium occurs in small proportions
in a number of fire-clays, including some of those of the Stourbridge
district, and glass melted in pots containing this element is liable to
have its colour spoilt by taking up the vanadium from the clay.
_Sulphur_ is an element whose presence in various forms is liable
to affect the colour of glass in a variety of ways. The colouring
effects of sodium-, calcium-, cadmium-, and antimony-sulphides have
already been referred to. Sulphur probably never exists in glass in
the uncombined state at all, but sulphur and its oxides, which are
often contained in furnace gases, sometimes exert a very marked action
upon hot glass. The presence of sulphur gases in the atmospheres of
blowing-holes and annealing kilns is liable to produce in the glass
a peculiar yellowish milkiness which penetrates for a considerable
depth into the mass of the glass and cannot be removed by subsequent
treatment. Glass vessels, particularly if made of glass produced from
raw materials among which salt-cake has figured, are also affected by
contact with fused sulphur or its vapour, the effect being a gradual
disintegration of the glass. The precise mechanism of these actions
is not known at present, but they probably consist in the formation
of sulphur compounds within the glass, possibly giving rise to an
evolution of minute bubbles of gas.
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