_Selenium_, which is chemically so closely related to sulphur, is
a relatively rare element, which is, however, finding some use
in glass-manufacture as a colouring and a decolouring agent. The
introduction of selenium or of its compounds under suitable conditions
into a glass mixture produces or tends to produce a peculiar
yellowish-pink coloration, the intensity of the colour produced being
dependent upon the chemical nature of the glass as a whole and, of
course, upon the amount of selenium left in the glass at the end of the
melting process, this latter in turn depending upon the duration and
temperature of the process in question. The pink colour of selenium
glass is best developed in those containing barium as a base, but it is
also developed in lead glasses, while soda-lime glasses do not show the
colour so well. As a “decolouriser” the action of selenium is entirely
that of producing a complementary colour which is intended to “cover”
the green or blue tint of the glass; where the depth of the tint to
be “covered” is small, selenium can be used very successfully in this
way, although it is a relatively costly substance for such a purpose.
No oxidising or “cleansing” action can be ascribed to selenium or its
compounds.
_Chromium_ is one of the most intensely active colouring substances
that are available for the glass-maker, and it is accordingly used
very extensively. It has the advantage of relative cheapness, and can
be conveniently obtained and introduced into glass in the form of pure
compounds whose colouring effect can be accurately anticipated; the
colours produced by the aid of chromium have the further advantage of
being very constant in character, being little affected by oxidising
or reducing conditions, and only very slightly by the length or
temperature of the melting process. The rate of cooling, in fact,
appears to be the only factor that materially affects the colours
produced by compounds of chromium. The colours produced by chromium
alone are various depths of a bright green, the depth varying, of
course, with the proportion of chromium that is present in the glass
and with the purity of the glass itself. Very frequently, chromium
is used in conjunction with either iron or copper to produce various
tints of “cold blue” and “celadon green” respectively. This element
is most usually introduced into the glass mixture in the form of
potassium bichromate; although other compounds might be employed,
this substance presents several advantages to the glass maker. In
the first place, since the colouring effect of chromium is very
intense, it must be used in very small quantities, and if chromic
oxide itself were used, the weighing would have to be carried out with
extreme care; potassium bichromate, however, contains a much smaller
proportion of the effective colouring substance, so that much larger
weights can be employed, and the accuracy of weighing required is
proportionately reduced.
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