colour produced in glass by the addition of very small proportions of
manganese is approximately complementary to the greenish-blue tinge of
the less pure varieties of ordinary glass; the addition of manganese in
suitable proportions to such glass therefore results in the production
of a glass which transmits light of approximately neutral, usually
slightly yellow, colour, the increased total absorption only becoming
noticeable in large pieces. This “covering” of the greenish tinge is
generally most completely successful in the case of soda-flint glasses,
but the method is also used to a certain extent in the case of the
soda-lime glasses used for sheet and plate-glass manufacture. Manganese
added to glass for this purpose is generally introduced into the
mixture in the form of the powdered black oxide (manganese dioxide),
which is available as a natural ore in a condition of sufficient
purity. Added in this form, the manganese compound exerts a double
action, the decomposition of the dioxide resulting in the liberation of
oxygen within the mass of melting glass, and this oxygen itself exerts
a favourable influence on the resulting colour of the glass, since it
removes organic materials whose subsequent reducing action would be
deleterious, and it also converts all iron compounds present into the
more highly-oxidised (ferric) state in which their colouring effects
are less intense. The actual colouring effect of the manganese itself
is, of course, afterwards developed, and produces the effects discussed
above.
The “covering” of the greenish tints due to iron and other compounds
is only possible when these are present in very small proportions.
When larger quantities of these substances have been introduced into
the glass the addition of manganese modifies the resulting colour, but
is no longer able to neutralise it. A very large range of colours can
be obtained by using various proportions of iron and manganese, the
best-known of these being the warm brown tint known as “hock-bottle,”
while all shades between this and the bright green of iron and the
purple of manganese can be obtained by suitable mixtures. What has been
said above as to the sensitiveness of manganese colours applies with
even greater force to these mixed tints, since here both the iron and
the manganese compounds are liable to undergo changes of oxidation.
Copper-manganese and chromium-manganese colours are also used, as
indeed almost any number of colouring ingredients may be simultaneously
introduced into a glass mixture, the resulting colour being, as a rule,
purely additive.
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