_Iron_ is so widely distributed among the materials of the earth’s
crust that it is exceedingly difficult to exclude it entirely from
any kind of glass, although the purest varieties of glass contain the
merest traces of this element. Cheaper varieties of glass, however,
always contain iron in measurable quantity, while the cheapest kinds of
glass contain considerable proportions of this element. The colouring
effects of iron have already been alluded to at various points in the
earlier chapters as well as in the section on manganese just preceding.
Little further remains to be said here. Just as the less highly
oxidised compounds of iron--_i.e._, the “ferrous” compounds--always
show a decided green tint, so glasses containing iron when melted under
the usually prevalent reducing conditions of a glass-making furnace,
show a decided green tint whose depth depends upon the amount of
iron present, provided no manganese or other “decolouriser” has been
introduced. “Ferrous” compounds are, however, readily converted into
the more highly oxidised or “ferric” state by the action of oxidising
agents, and this change can also be brought about in molten glass by
the action of such substances as nitrates or other sources of oxygen.
The ferric compounds, however, show characteristic yellow tints which
are much less intense and vivid than the corresponding green colours
of the “ferrous” series, and a similar result is brought about by the
oxidation of iron compounds contained in glass; hence the “washing” or
cleansing effects ascribed to oxidising agents introduced in the fusion
of glass. It should, however, be borne in mind that the oxidation of
other substances besides iron compounds, viz., organic matter, carbon
and sulphur compounds, may, and probably does, play a most important
part in this process in the case of most varieties of glass.
_Nickel_ exerts a powerful colouring influence on glass, in accordance
with the fact that most of the other compounds of this element are
also deeply coloured. The exact colour produced in glass depends
upon the nature of the glass and on the condition of oxidation in
which the nickel is present. The colours, however, are usually of
a greenish-brown tint, although brighter colours can be produced
by nickel under special conditions. This element is not, however,
much used as a colouring agent in practice, although it has been
advocated as a “decolouriser.” The writer is not, however, aware
that it has ever been successfully used for this purpose, and, in
fact, the colours to which it gives rise do not appear to be even
approximately complementary to the ordinary green and blue tints which
“decolourisers” are intended to cover.
Public-domain text, read in full here on John Shaqi.
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