Optical glass differs so widely from all other varieties of glass that
its manufacture may almost be regarded as a separate industry, to
which, indeed, a separate volume could well be devoted. In the present
chapter we propose to give an outline of the most important properties
of optical glass, and in the next chapter to describe the more
important features of the processes used in its production.
The properties which affect the value of optical glass may roughly be
divided into two groups. The first group comprises the specifically
“optical” properties--_i.e._, those directly influencing the behaviour
of light in its passage through the glass, while the second group
covers those properties of a more general nature, which are of special
importance in glass that is to be used for optical purposes.
_Optical Properties of Glass._--The most essential property of glass
in this respect is homogeneity. We have already indicated that glass
can never be regarded as a definite chemical substance or compound,
but that it usually consists of mutual solutions of various complex
silicates, borates, etc. Solutions being of the very nature of mixtures
of two or more different substances, it follows that they can only
become homogeneous when _complete_ mixing has taken place. We have
a familiar example of the formation of such a solution when sugar is
dissolved in water. The water near the sugar becomes saturated with
sugar and of different density from the remaining water; if the liquid
is _slightly_ stirred a very characteristic phenomenon makes its
appearance--the pure water and the dense sugar solution do not at once
mix completely, the denser liquid remaining for a time disseminated
throughout the whole fluid mass in the form of more or less fine lines,
sheets, or eddies, and these are visible because the imperfectly mixed
liquids have different effects on the light passing through them. In
the case of sugar-water we are, however, dealing with a very mobile
liquid, and a few turns of a tea-spoon suffice to render the mixture
complete, and the liquid, which for a few moments had appeared turbid,
becomes homogeneous and transparent. In the case of glass, when the
raw materials are melted together, a mixture is formed of liquids of
differing densities similar to that which was temporarily formed in
the sugar-water solution. Molten glass, however, is never so mobile
a liquid as ordinary water, nor is it in the ordinary course of
manufacture subjected to any such thorough mixing action as that which
is produced by a spoon in a glass of water. In glass as ordinarily
manufactured, therefore, it is not surprising to find that the lack of
homogeneity which originates during the melting persists to the end.
Its effects can be traced whenever a thick piece of ordinary glass is
carefully examined, when the threads or layers of differing densities
can be recognised in the form of minute internal irregularities in the
glass.
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