of glass, having average optical properties and showing dispersive
powers roughly conforming to the law of inverse proportionality with
refractive index which governs the older varieties of optical glass,
are chemically stable substances, showing little tendency to undergo
either chemical changes or to crystallise during cooling, the more
extreme glasses exhibit these undesirable features to an increasing
extent the more nearly the limit of our present range is approached.
As the chemical composition of a glass is “forced” by the addition
of special substances intended to affect its optical properties in
an abnormal direction, so the chemical and physical stability of the
glass is rapidly lessened. The more extreme glasses, in fact, behave as
active chemical agents readily entering into reaction or combination
even with relatively inert substances in their environment--they act
vigorously upon the fire-clay vessels in which they are melted, and
they are readily attacked by acids, moisture or even warm air, when in
the finished condition, while many of them can only be prevented from
assuming the condition of a crystalline (and opaque) agglomerate by
being rapidly cooled through certain critical ranges of temperature.
A limit to the possibility of production is set by these tendencies
when they exceed a certain amount--a point being reached where it
ceases to be practicable to overcome the tendency of the glass to
self-destruction. On the lines of our present glasses, therefore, it
does not appear hopeful to look for any considerable extension of the
range of our optical media. On the other hand, as the known optical
properties of transparent crystalline minerals show, a much greater
range of optical constants would become available if it were possible
to manufacture artificial mineral _crystals_ of sufficient size and
purity for optical purposes, and the author believes that in this
direction progress in optical materials is ultimately bound to lie[1].
[1] See a Paper by the present author on “Possible Directions
of Progress in Optical Glass”--Proceedings of the Optical
Convention, London, 1905.]
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