In addition to possessing the requisite optical constants, a good
colour and perfect homogeneity, certain other properties are essential
in good optical glass. These are the general physical and chemical
qualities which are essential in all good glass, but especially
emphasised by the fact that the requirements for optical glass are more
stringent than for any other variety of the material. Thus chemical
stability is of the greatest importance, for the best lenses would
soon become useless if the action of atmospheric moisture were to
affect them appreciably--the polished surfaces would rapidly become
dull and the whole lens would soon be rendered useless. The conditions
governing the chemical stability of glass and the methods of testing
this quality have already been indicated (Chapters I. and II.). The
harder varieties of optical glass, such as the glasses quoted in the
above table under the names of “Hard Crown” and Boro-Silicate Crown,
are probably among the most durable and chemically resistant of all
varieties of glass, but as we have already indicated, when extreme
optical properties are required, the necessary chemical composition of
the glass always entails a sacrifice of this great chemical stability,
until a limit is reached where valuable optical properties no longer
counterbalance the serious disadvantage of a chemical composition
which renders the glass liable to rapid disintegration. In certain
special cases it is, perhaps, possible to protect lenses made of such
unstable glass by covering them with cemented-on lenses of stable
glass, but this device entails concomitant limitations in the design
of the optical system and is, therefore, rarely used. In any case,
however, it is well for the lens-designer to consider the relative
stability of the glasses employed when arranging the order in which
they are to be used, since it is obviously preferable to put a hard,
durable glass on the outside of his system, where it is most directly
exposed to atmospheric moisture, and is also subject to handling and
“cleaning” by inexpert hands. This latter factor is a very important
one for the life of any lens. In the first place, a glass surface is
very seriously affected by the minute film of organic matter which is
left upon it when it has been touched with even a clean finger; unless
the glass is of the best quality in this respect, such fingermarks
readily develop into iridescent spots and may even turn into black
stains. Particles of dust allowed to settle on the surface of the glass
will affect it in the same way, so that the protection afforded by mere
mechanical enclosure in the tube of an instrument is of decided value
in preserving a glass surface. It should, however, be noted that in
some instances the interior metal surfaces of optical instruments are
varnished with substances that give off vapours for a long time after
the instrument is completed, and in that case the inside lenses are apt
to be tarnished in consequence.
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