Another property which is essential in optical glass of the highest
quality is that of freedom from internal strains. This subject will be
again referred to later in connection with the annealing processes used
in the manufacture of optical glass, and it need only be mentioned here
that the presence of internal strain is readily recognised in glass,
by the aid of the polariscope. Perfectly annealed glass, entirely free
from internal strains, produces no effect upon a beam of polarised
light passing through it, while even slightly strained glass becomes
markedly doubly-refracting. For many purposes of optics this double
refraction becomes undesirable or even inadmissible, especially as it
is accompanied by small variations in the effective index of refraction
of various portions of the mass of glass. Further, if the amount of
double refraction observed is at all serious it indicates a state
of strain which may easily lead to the fracture of the whole piece,
particularly when undergoing the earlier stages of the grinding process
or if exposed to shocks of any sort. As will be seen below, perfectly
annealed glass is obtainable, but very special means are required for
its production, and the optician should for that reason avoid making
unnecessarily extreme demands in this direction. The very _small_
amount of double refraction frequently found in the better class of
optical glass is entirely harmless for most purposes.
CHAPTER XIII.
OPTICAL GLASS.
The process of manufacturing the best qualities of optical glass may
be briefly described as consisting in obtaining a crucible full of
the purest and most homogeneous glass, and then allowing it to cool
slowly and to solidify _in situ_. From the resulting mass of glass
the best pieces are picked and moulded into the desired shape for
optical use. It will be seen at once that in this process there is
an essential difference from all others that have been described in
this book--viz., that the glass is never removed from the melting-pot
while molten, and that none of the operations of gathering, pouring,
rolling, pressing, or blowing are applied to it. The reason for this
apparently irrational mode of procedure lies in the fact that the
perfect homogeneity essential for optical purposes can only be attained
by laborious means, and can then only be retained if the glass is left
to solidify undisturbed; any movement by the introduction of pipes or
ladles would result in the contamination of the glass by striæ and
other objectionable defects.
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