When, finally, sufficient material has been introduced to fill the pot
completely, the next stage of the process commences. When the last
charge of raw materials has melted, the glass in the pot is left in the
state of a more or less viscous liquid full of bubbles of all sizes;
it is essential that these bubbles should escape and leave the glass
pure and “fine,” and this result can only be achieved by raising the
temperature of the furnace and allowing the glass to become more fluid,
while the rise of temperature also causes the bubbles to expand owing
to the expansion of the gas contained in them. In both ways, rise of
temperature facilitates the escape of the bubbles, and the furnace
is therefore heated to the full, and this extreme heat is maintained
until the glass is free from bubbles. In the case of the more fusible
glasses the temperature required for this purpose is not excessively
high, and, indeed, in the case of these glasses care is taken to avoid
too high a temperature, as it entails other disadvantages. In the case
of the harder crown glasses, however, the difficulty lies in producing
an adequately high temperature without at the same time endangering
the life of furnace and crucible. The difficulty of freeing the molten
glass from bubbles constitutes one of the causes that limit the range
of our optical glasses in one direction--still harder glasses could be
melted, but it would not be feasible to maintain a temperature high
enough to render them fluid enough to “fine.”
In the case of other kinds of glass, again, it becomes impossible to
entirely remove the bubbles from the molten mass even when very hot and
very fluid. The exact cause is not known, but in some kinds of glass
the bubbles formed are so minute that even when the glass is perfectly
mobile the bubbles show no tendency to escape, while in other kinds of
glass there appears to be a steady evolution of minute bubbles as soon
as the temperature is raised with a view to removing those already in
the glass. As this property attaches to some of the most valuable of
the newer varieties of optical glass, opticians and the public have
learnt to put up with the presence of minute bubbles in the lenses
and prisms made of these glasses. These bubbles are, however, very
minute and do not interfere with the optical performance of the lenses,
&c., except to the extent of arresting and scattering the very small
proportion of light that falls upon them; their presence is therefore
to be regarded as a small but unavoidable drawback to the use of
glasses which offer advantages that completely outweigh this defect.
Public-domain text, read in full here on John Shaqi.
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