The glass used for the production of tubing varies very widely
according to the purpose for which the product is intended. Almost
any of the more usual varieties of glass can be readily drawn out
into tubes, and the choice of the kind of glass to be employed is
therefore left to other considerations. Tubing required for the use of
the lamp-worker, _i.e._, for the production of instruments or other
articles by the aid of the glass-blower’s blow-pipe, must have the
capacity of undergoing repeated cooling and heating without showing
signs of crystallisation (devitrification), while reasonable softness
in the flame is also required. For this purpose, also, glass containing
lead is not admissible, since this would blacken under the influence
of the blow-pipe flame. Soda-lime glasses rather rich in alkali are
most frequently used for these purposes; one consequence of their
chemical composition, however, is that such glass tends to undergo
decomposition when stored for any length of time, more especially in
damp places. Frequently this decomposition only manifests itself on
heating the glass in a flame, when it either flies to pieces or turns
dull and rough on the surface. Such glass is sometimes said to have
“devitrified,” but this is not really the case; what has actually
happened is that the atmospheric moisture has penetrated for some
little distance into the thickness of the glass, probably hydrating
some of the silica; on heating, this moisture is driven off, with the
result that either a few large cracks, or innumerable fine ones, are
formed. In the latter case these do not readily disappear when the
glass is softened and the dull, rough surface is left at the end of the
operation.
For purposes where the glass is to be exposed to high temperatures,
tubing made of so-called “hard glass” is employed. This is practically
a form of Bohemian crystal glass, the chemical composition being
that of a potash-lime glass rather rich in lime. To some extent this
Bohemian hard glass has been superseded by the special “combustion
tube” glass manufactured by Schott, of Jena. This is a very refractory
borosilicate glass containing some magnesia; it certainly withstands
higher temperatures than hard Bohemian glass, and is rather less
sensitive to changes of temperature; on the other hand, it has the
inconvenient property of showing a white opalescence when it has once
been heated, and this, after a time, renders the glass completely
opaque.
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