For many purposes, where heat-resisting qualities are chiefly required,
ordinary glass has now a formidable rival in the shape of vitrified
silica, which is now available as a satisfactory commercial product.
This substance offers the great advantage that for most ordinary
purposes it may be regarded as entirely infusible, since the intense
heat of an oxygen-fed flame is required to soften or melt the silica.
Further, vitreous silica has an extremely low coefficient of expansion,
and appears also to have a rather high coefficient of thermal
conductivity. The result is that tubes and other articles made of
this material possess an astonishing amount of thermal endurance (see
Chapter II.).
A white-hot tube or rod of this material can be plunged into cold water
with impunity, and no special care need be exercised in heating or
cooling articles made of this substance, unless articles of great size
and thickness are involved, and even with these only little caution
is needed. The only disadvantages which must be balanced against the
great advantages just named lie in the relatively high cost of the
articles and in their somewhat sensitive behaviour to certain chemical
influences. As regards cost, vitreous silica is at present available in
two different forms; in the first form it resembles ordinary glass very
closely in appearance, the shape and finish of the tubes and vessels
of this kind having undergone very great improvements quite recently.
This silica glass has, in fact, been worked from molten silica in a way
more or less analogous to that in which ordinary glass is worked, the
great extra cost of the silica ware being due, in part, at all events,
to the extremely high temperature required for melting and working this
material; ordinarily, in the production of the class of silica ware
now referred to, this heat is generated by the liberal--and therefore
expensive--use of oxygen gas. In great contrast to this glass-like,
transparent silica ware is the other form in which this material is
available. This is a series of products obtained from the fusion of
silica in special forms of electric furnace; in this ware the minute
bubbles so readily formed in the fusion of all forms of quartz are not
even partially eliminated, and by their presence--often in the form of
long-drawn-out, capillary hollows--they impart to this ware its very
characteristic milky appearance. The price of this product, which is
mostly used in the form of tubes, although such articles as basins,
crucibles, and even muffles of considerable size are available, is much
lower than that of the transparent variety, being in fact decidedly
lower than that of the best porcelain; on the other hand, even this
price is considerably above that of the best glass tubing.
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