In addition to these difficulties, which arise largely from
considerations of a commercial nature, the writer of a book on glass
is further confronted with technical difficulties of no inconsiderable
order. As already indicated, the aim of the present author has been to
describe processes from the point of view of principles and methods
rather than as mere rule-of-thumb descriptions of manufacturing
manipulations, but in doing this he is met at every turn by the fact
that from the scientific side the greater part of the field of glass
manufacture is a “terra incognita.” In making this statement the
labours of many eminent scientific workers are by no means forgotten,
but the entire field is so large and beset with such great experimental
difficulties that even the labours of a list of investigators that
includes the names of Fraunhofer and Faraday, Stokes, Hopkinson, Abbé
and Schott, have resulted in little more than an accumulation of
empirical data which, while they have been productive of great direct
practical results, have left the science of glass still in a very
elementary condition. To take two examples in illustration of this
fact we may mention the question of the connection between chemical
composition and any of the physical properties of glass, such as
refraction and dispersion of light, and on the more mechanical side the
question why all processes, such as rolling or moulding, which involve
the contact of hot glass with metal result in a roughening of the
glass surface. The former question has been studied by several of the
investigators named above, Schott and Abbé having particularly devoted
an enormous amount of labour and money to the study of the question
with results which have proved disappointing from the scientific point
of view. By prolonged experimenting and the employment of a costly
system of trial and error an important series of novel and useful
glasses has been produced by these workers, but no law by whose aid the
optical properties of a glass of given chemical composition could be
predicted has yet been discovered, and as a summary of the known facts
only the vaguest general principles are available for the guidance
of those who wish to produce glasses of definite properties. The
same applies in a similar degree to most of the other properties of
glass, with the exception, perhaps, of density and thermal expansion;
attempts to generalise from the known data of a limited number of
glasses generally meet with unqualified failure. The conclusion which
one is forced to admit is that the fundamental principles underlying
the nature and constitution of glasses have yet to be discovered.
A study of the other question mentioned above as an example of the
limitations of our knowledge leads to the same conclusion; an almost
endless succession of inventors have busied themselves with devices
for overcoming the roughening action of rollers and moulds upon
glass, but without any real success. A long list of other examples
Public-domain text, read in full here on John Shaqi.
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